Innovative solvent for two-phase catalysis - Ionic fluids

被引:30
|
作者
Wasserscheid, P [1 ]
机构
[1] Rhein Westfal TH Aachen, Inst Tech Chem & Makromol Chem, D-52074 Aachen, Germany
关键词
MOLTEN-SALT; PHOSPHINE-LIGANDS; LIQUIDS; COMPLEXES; HYDROFORMYLATION; ELECTROCHEMISTRY; SPECTROSCOPY; DIMERIZATION; ALKENES;
D O I
10.1002/ciuz.200390006
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ionic liquids are low melting salts which represent a new class of non-molecular, ionic solvents. By combining different cations and anions a large number of liquids with very different physical and chemical properties can be obtained. It is possible to optimize the ionic medium for a specific application by the careful choice of the ion combination. Ionic liquids are interesting substitutes for organic solvent in catalytic reactions for many reasons: Besides their non-volatile nature offering significant engineering advantages, the unusual solubility properties of these liquids enable new multiphasic catalytic reactions.
引用
收藏
页码:52 / 63
页数:12
相关论文
共 50 条
  • [21] A model of a nonisothermal two-phase flow of compressible fluids
    Feireisl, Eduard
    Petcu, Madalina
    She, Bangwei
    MATHEMATICAL METHODS IN THE APPLIED SCIENCES, 2023, 46 (08) : 9362 - 9377
  • [22] An extended finite element method for two-phase fluids
    Chessa, J
    Belytschko, T
    JOURNAL OF APPLIED MECHANICS-TRANSACTIONS OF THE ASME, 2003, 70 (01): : 10 - 17
  • [23] Phase behavior of ionic liquids (II) Aqueous two-phase
    Xia, Hansong
    Yu, Jiang
    Hu, Xuesheng
    Liu, Qingfen
    Liu, Huizhou
    Huagong Xuebao/Journal of Chemical Industry and Engineering (China), 2006, 57 (09): : 2149 - 2151
  • [24] Hydrodynamics studies of the behaviour of traditional and two-phase ionic liquid solvent systems in countercurrent chromatography (CCC)
    Lange, Vicky
    Brown, Leslie
    Angeli, Panagiota
    CHEMICAL ENGINEERING SCIENCE, 2018, 192 : 551 - 564
  • [25] AN INNOVATIVE TWO-PHASE FLOW PUMP AND SEPARATOR SOLUTION
    Gruselle, Francois
    Steimes, Johan
    Hendrick, Patrick
    PROCEEDINGS OF THE ASME TURBO EXPO 2011, VOL 4, 2012, : 1079 - 1088
  • [26] Comparison of oxoperoxophosphatotungstate phase transfer catalysis with methyltrioxorhenium two-phase catalysis for epoxidation by hydrogen peroxide
    Salles, L
    Brégeault, JM
    Thouvenot, R
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 2000, 3 (03): : 183 - 187
  • [27] ANALYSIS OF A PHASE-FIELD MODEL FOR TWO-PHASE COMPRESSIBLE FLUIDS
    Feireisl, Eduard
    Petzeltova, Hana
    Rocca, Elisabetta
    Schimperna, Giulio
    MATHEMATICAL MODELS & METHODS IN APPLIED SCIENCES, 2010, 20 (07): : 1129 - 1160
  • [28] Selection of aqueous two-phase solvent systems in CCC
    Gong, Y
    Huang, JG
    Liu, XJ
    Li, ZC
    JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES, 2003, 26 (9-10) : 1509 - 1520
  • [29] Ionic-Liquid|Water two-phase systems
    Kakiuchi, Takashi
    ANALYTICAL CHEMISTRY, 2007, 79 (17) : 6442 - 6449
  • [30] Two-phase biocatalysis using ionic liquids.
    Kragl, U
    Eckstein, M
    Hameister, D
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U65 - U65