All-Printed Green Micro-Supercapacitors Based on a Natural-derived Ionic Liquid for Flexible Transient Electronics

被引:39
|
作者
Migliorini, Lorenzo [1 ]
Piazzoni, Claudio [1 ]
Pohako-Esko, Kaija [2 ]
Di Girolamo, Marta [1 ]
Vitaloni, Andrea [1 ]
Borghi, Francesca [1 ]
Santaniello, Tommaso [1 ]
Aabloo, Alvo [2 ]
Milani, Paolo [1 ]
机构
[1] Univ Milan, Interdisciplinary Ctr Nanostruct Mat & Interfaces, Dept Phys, Via Celoria 16, I-20133 Milan, Italy
[2] Univ Tartu, Inst Technol, Nooruse 1, EE-50411 Tartu, Estonia
关键词
cellulose; choline lactate; green supercapacitors; printing technologies; spray casting; transient electronics; PHYSICAL-PROPERTIES; TOXICITY; ELECTROLYTES; NANOCOMPOSITES; NANOPARTICLES; CONDUCTIVITY; CAPACITANCE; PERFORMANCE; FABRICATION; DEPOSITION;
D O I
10.1002/adfm.202102180
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The fabrication and characterization of green, flexible, and ultra-thin supercapacitors that are able to operate above 1.5 V is reported, using an all-printed fabrication process. The devices are produced by aqueous spray casting of a natural-derived electrolyte ionogel composed by 2-hydroxyethyl cellulose and by the ionic liquid choline lactate, while the electrodes are composed of highly porous nanostructured carbon films deposited by supersonic cluster beam deposition (SCBD). The obtained supercapacitors (device thickness < 10 mu m) are stable to bending and they possess power values up to 120 kW kg(-1). The combination of aqueous spray casting and SCBD constitutes a versatile, scalable, and eco-friendly fabrication process able to directly print interconnected elements suitable for transient electronic systems.
引用
收藏
页数:10
相关论文
共 41 条
  • [11] All-printed 3-dimensional micro-supercapacitors with homogeneous Ag interface: Achieving precision on curved surfaces through Electrohydrodynamic jet printing
    Jung, Sujin
    Mandal, Debasish
    Min, Won Kyung
    Jeong, Jong Yeub
    Lee, I. Sak
    Chung, Jusung
    Singu, Bal Sydulu
    Kim, Hansung
    Kim, Hyun Jae
    CHEMICAL ENGINEERING JOURNAL, 2024, 497
  • [12] Ionic liquid pre-intercalated MXene films for ionogel-based flexible micro-supercapacitors with high volumetric energy density
    Zheng, Shuanghao
    Zhang, Chuanfang
    Zhou, Feng
    Dong, Yanfeng
    Shi, Xiaoyu
    Nicolosi, Valeria
    Wu, Zhong-Shuai
    Bao, Xinhe
    JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (16) : 9478 - 9485
  • [13] A Printable Metallic Current Collector for All-Printed High-Voltage Micro-Supercapacitors: Instantaneous Surface Passivation by Flash-Light-Sintering Reaction
    Chae, Changju
    Han, Jae Hee
    Lee, Sun Sook
    Choi, Youngmin
    Kim, Tae-Ho
    Jeong, Sunho
    ADVANCED FUNCTIONAL MATERIALS, 2020, 30 (25)
  • [14] Flexible, in-plane, and all-solid-state micro-supercapacitors based on printed interdigital Au/polyaniline network hybrid electrodes on a chip
    Hu, Haibo
    Zhang, Kun
    Li, Shuxin
    Jia, Shulin
    Ye, Changhui
    JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (48) : 20916 - 20922
  • [16] High-performance, flexible, solid-state micro-supercapacitors based on printed asymmetric interdigital electrodes and bio-hydrogel for on-chip electronics
    Zhao, Wen
    Wei, Lu
    Fu, Qiangang
    Guo, Xin
    JOURNAL OF POWER SOURCES, 2019, 422 : 73 - 83
  • [17] All-printed, interdigitated, freestanding serpentine interconnects based flexible solid state supercapacitor for self powered wearable electronics
    Rajendran, Vinoth
    Mohan, A. M. Vinu
    Jayaraman, Mathiyarasu
    Nakagawa, Tatsuo
    NANO ENERGY, 2019, 65
  • [18] On chip, all solid-state and flexible micro-supercapacitors with high performance based on MnOx/Au multilayers
    Si, Wenping
    Yan, Chenglin
    Chen, Yao
    Oswald, Steffen
    Han, Luyang
    Schmidt, Oliver G.
    ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (11) : 3218 - 3223
  • [19] Carbon-Based Flexible and All-Solid-State Micro-supercapacitors Fabricated by Inkjet Printing with Enhanced Performance
    Zhibin Pei
    Haibo Hu
    Guojin Liang
    Changhui Ye
    Nano-Micro Letters, 2017, 9 (02) : 68 - 78
  • [20] Carbon-Based Flexible and All-Solid-State Micro-supercapacitors Fabricated by Inkjet Printing with Enhanced Performance
    Pei, Zhibin
    Hu, Haibo
    Liang, Guojin
    Ye, Changhui
    NANO-MICRO LETTERS, 2017, 9 (02)