Synthesis and the crystal structure of aqua-dioxo-nitrato-(2,2′,6′,2"-terpyridine)-neptunium(V) [NpO2(NO3)(Terpy)(H2O)]

被引：6
|
作者：
Budantseva, NA
Andreev, GB
Fedoseev, AM
Antipin, MY
Krupa, JC
机构：
[1] Russian Acad Sci, Inst Phys Chem, Moscow 119991, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[3] CNRS, IN2P3, Inst Phys Nucl, F-91406 Orsay, France
来源：
CRYSTALLOGRAPHY REPORTS | 2003年 / 48卷 / 01期
关键词：
Oxygen; Nitrogen; Nitrate; Crystal Structure; Water Molecule;
D O I：
10.1134/1.1541744
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the [NpO2(NO3)(Terpy)(H2O)] complex between pentavalent neptunium and 2,2',6',2"-terpyridine is determined. The crystal data are as follows: a = 11.130(3) Angstrom, b = 7.916(2) Angstrom, c = 18.324(5) Angstrom, beta = 100.873(6)degrees, V = 1585.5(8) Angstrom(3), Z = 4, space group is P2(1)/n, R = 0.044, and wR(F-2) = 0.092. The coordination polyhedron of the Np atom is a pentagonal bipyramid whose equatorial plane includes three nitrogen atoms of the Terpy molecule and two oxygen atoms of the nitrate ion and the water molecule. (C) 2003 MAIK "Nauka/Interperiodica".
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页码：58 / 60
页数：3
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