Effects of Cr and Fe co-doping on structural, optical, electrical and magnetic properties of titanium dioxide (TiO2)

被引：17
|
作者：
Waseem, Salma [1 ]
Anjum, Safia [1 ]
Mustafa, Lubna [1 ]
Dar, Anum [2 ]
Bashir, Farooq [2 ]
Zia, Rehana [1 ]
机构：
[1] Women Univ, Lahore Coll, Dept Phys, Lahore, Pakistan
[2] Women Univ, Lahore Coll, Cent Lab, Lahore, Pakistan
来源：
MATERIALS SCIENCE-POLAND | 2015年 / 33卷 / 03期
关键词：
dilute magnetic semiconductors; rutile; grain size; magnetic properties; resistivity;
D O I：
10.1515/msp-2015-0092
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A series of Ti0.9F0.1--xCrxO2 (where x = 0.0, 0.02, 0.04, 0.6, 0.08, 0.10) was synthesized using the powder metallurgy route. The structural, morphological, magnetic, optical and electrical properties were investigated by X-ray diffractometry (XRD), Raman spectroscopy, scanning electron microscopy (SEM), vibrating sample magnetometry (VSM), UV-Vis spectroscopy and four probe technique, respectively. The rutile phase was confirmed by XRD analysis which was also verified by Raman spectroscopy. It was observed that the grain size increased as the concentration of Cr increased. M-H loops extracted from VSM analysis revealed anti-ferromagnetic, weak ferromagnetic and paramagnetic behaviors at room temperature. The band gap energy and resistivity measurements exhibited the semiconducting nature of Ti0.9Fe0.1-xCrxO2 based diluted magnetic semiconductors.
引用
收藏
页码：508 / 514
页数：7
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