Bis[bis(N,N-diethyldithiocarbamato)zinc(II)](trans-1,2-bis(4-pyridyl)ethylene)trans-1,2-bis(4-pyridyl)ethylene lattice adduct

被引：23
|
作者：
Lai, CS [1 ]
Tiekink, ERT [1 ]
机构：
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2003年 / 17卷 / 04期
关键词：
crystal structure; zinc; dithiocarbamate; diimine adduct; lattice adduct;
D O I：
10.1002/aoc.420
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The dimeric and centrosymmetric structure of [Zn(S2CNEt2)2(trans-NC5H4C(H)=C(H)C5H4N)](2) shows bidentate coordination by the dithiocarbamate ligands and a distorted square pyramidal geometry for zinc, defined by a NS4 donor set with the N atom in the apical position. The compound co-crystallises with a centrosymmetric molecule of trans-NC5H4C(H)=C(H)C5H4N that does not form a significant interaction to the Zn atom. Copyright (C) 2003 John Wiley Sons, Ltd.
引用
收藏
页码：251 / 252
页数：2
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