Synthesis, characterization, and photophysical and photochemical properties of 3-(4-phenyloxy)coumarin containing metallo- and metal-free phthalocyanines

被引：6
|
作者：
Kartaloglu, Nurullah [1 ]
Esenpinar, Aliye Ash [2 ]
Bulut, Mustafa [1 ]
机构：
[1] Marmara Univ, Fac Arts & Sci, Dept Chem, Istanbul, Turkey
[2] Kirklareli Univ, Dept Chem, Kirklareli, Turkey
来源：
TURKISH JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 06期
关键词：
Coumarin (2H-chromen-2-one); benzocoumarin; phthalocyanine; fluorescence quenching; singlet oxygen; quantum yield; ZINC PHTHALOCYANINE; PHOTOSENSITIZERS; SUBSTITUENTS; DERIVATIVES; COMPLEXES;
D O I：
10.3906/kim-1405-84
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of novel zinc, cobalt, indium, and metal-free phthalocyanines carrying four 3-(4-phenyloxy)coumarins in the periphery/nonperiphery were prepared by cyclotetramerization of 344-(3,4-dicyanophenyloxy)phenyl]coumarin (2)/3-[4-(2,3-dicyanophenyloxy)phenyl]coumarin (3). The novel chromogenic compounds were characterized by elemental analysis, H-1 NMR, mass spectra, F-IR, and UV-vis spectral data. The effects of the coumarin units on the zinc, indium, and metal-free phthalocyanine complexes (2a/3a, 2c/3c, 2d/3d) were also investigated.
引用
收藏
页码：1102 / 1117
页数：16
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