Synthesis, characterization, and photophysical and photochemical properties of 3-(4-phenyloxy)coumarin containing metallo- and metal-free phthalocyanines

被引：6

作者：

Kartaloglu, Nurullah ^{[1
]}

Esenpinar, Aliye Ash ^{[2
]}

Bulut, Mustafa ^{[1
]}

机构：

[1] Marmara Univ, Fac Arts & Sci, Dept Chem, Istanbul, Turkey

[2] Kirklareli Univ, Dept Chem, Kirklareli, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 06期

关键词：

Coumarin (2H-chromen-2-one); benzocoumarin; phthalocyanine; fluorescence quenching; singlet oxygen; quantum yield; ZINC PHTHALOCYANINE; PHOTOSENSITIZERS; SUBSTITUENTS; DERIVATIVES; COMPLEXES;

D O I：

10.3906/kim-1405-84

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of novel zinc, cobalt, indium, and metal-free phthalocyanines carrying four 3-(4-phenyloxy)coumarins in the periphery/nonperiphery were prepared by cyclotetramerization of 344-(3,4-dicyanophenyloxy)phenyl]coumarin (2)/3-[4-(2,3-dicyanophenyloxy)phenyl]coumarin (3). The novel chromogenic compounds were characterized by elemental analysis, H-1 NMR, mass spectra, F-IR, and UV-vis spectral data. The effects of the coumarin units on the zinc, indium, and metal-free phthalocyanine complexes (2a/3a, 2c/3c, 2d/3d) were also investigated.

引用

页码：1102 / 1117

页数：16

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