Vapor pressures of aqueous KCl and MgCl2 solutions from 273.16 to 643.15K

被引:2
|
作者
Shibue, Y [1 ]
机构
[1] Hyogo Univ Teachers Educ, Dept Nat Sci, Yashiro, Hyogo 6731494, Japan
关键词
vapor pressure; vapor-liquid equilibria; aqueous KCl solution; agueous MgCl2 solution;
D O I
10.1016/j.fluid.2004.10.008
中图分类号
O414.1 [热力学];
学科分类号
摘要
The Wagner-Pruss equation is modified for expressing the vapor pressures of aqueous KCl and MgCl2 solutions from 273.16 to 643.15 K. The salt concentrations are up to 20.7mass% for the H2O +KCl system and 20.9mass% for the H2O+MgCl2 system. This study adds the concentration-dependent terms to the Wagner-Pruss equation and multiplies the reduced temperature by T-c/647.096, where T-c is the critical temperature of the aqueous solution in Kelvin. (C) 2004 Elsevier B.V. All rights reserved.
引用
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页码:267 / 276
页数:10
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