Preparation and Properties of Polythiourethane/ZnS Nanocomposites with High Refractive Index

被引：18

作者：

Liu, Li ^{[1
,2
]}

Zheng, Zhen ^{[1
,2
]}

Wang, Xinling ^{[1
,2
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[2] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2010年 / 117卷 / 04期

关键词：

nanocomposites; polyurethanes; refractive index; nanocomposite; ZnS; polyurethane;

D O I：

10.1002/app.32009

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The inorganic-organic crosslinking polythiourethane/ZnS (PTU/ZnS) nanocomposites with high refractive index and transmittance were successfully prepared. The thiol-capped ZnS nanoparticles with a diameter of about 5 nm were fabricated into the molecular chains of PTU via the formed covalent bonds between the capped ZnS and the matrix. The investigations demonstrated the ZnS nanoparticles were uniformly dispersed in the PTU matrix even at high contents. The optical studies showed the refractive index of the highly transparent nanocomposite films linearly increased from 1.643 to 1.792 with the increase of the ZnS content. The structure, morphology, and other properties were also characterized by FTIR, NMR, AFM, XRD, DSC, TGA, etc. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 117: 1978-1983, 2010

引用

页码：1978 / 1983

页数：6

共 50 条

[31] High Refractive Index and Transparency Nanocomposites as Encapsulant for High Brightness LED packaging
Liu, Yan
Lin, Ziyin
Zhao, Xueying
Moon, Kyoung-sik
Yoo, Sehoon
Choi, J.
Wong, C. P.
2013 IEEE 63RD ELECTRONIC COMPONENTS AND TECHNOLOGY CONFERENCE (ECTC), 2013, : 553 - 556
[32] Development of high refractive ZnS/PVP/PDMAA hydrogel nanocomposites for artificial cornea implants
Zhang, Quanyuan
Su, Kai
Chan-Park, Mary B.
Wu, Hong
Wang, Dongan
Xu, Rong
ACTA BIOMATERIALIA, 2014, 10 (03) : 1167 - 1176
[33] INHOMOGENEITY OF THE REFRACTIVE-INDEX OF ZNS FILM
WU, QH
APPLIED OPTICS, 1987, 26 (18): : 3753 - 3754
[34] The Preparation and Characterization of ZnS/PMMA Nanocomposites
Li, Yuzhen
Zhang, Sanyuan
Gao, Lizhen
Chen, Wenjun
Gao, Lili
Zhang, Weike
Cui, Jiali
Yan, Shaohui
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (07) : 942 - 945
[35] Tailoring high-refractive-index nanocomposites for manufacturing of ultraviolet metasurfaces
Kang, Hyunjung
Oh, Dongkyo
Jeon, Nara
Kim, Joohoon
Kim, Hongyoon
Badloe, Trevon
Rho, Junsuk
MICROSYSTEMS & NANOENGINEERING, 2024, 10 (01)
[36] SIZE VARIATION OF PBS PARTICLES IN HIGH-REFRACTIVE-INDEX NANOCOMPOSITES
KYPRIANIDOULEODIDOU, T
CASERI, W
SUTER, UW
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (36): : 8992 - 8997
[37] Novel computational design of high refractive index nanocomposites and effective refractive index tuning based on nanoparticle morphology effect
Liu, Sipan
Islam, Md Didarul
Ku, Zahyun
Boyd, Darryl A.
Zhong, Yaxu
Urbas, Augustine M.
Smith, Evan
Derov, John
Nguyen, Vinh Q.
Kim, Woohong
Sanghera, Jasbinder S.
Ko, Yeongun
Genzer, Jan
Ye, Xingchen
Guo, Zhanhu
Seo, Eunice
Ryu, Jong E.
COMPOSITES PART B-ENGINEERING, 2021, 223
[38] Preparation and properties of a high refractive index optical resin prepared via click chemistry method
Luo, Chaoyun
Zuo, Jiandong
Yuan, Yanchao
Lin, Xuechun
Lin, Feng
Zhao, Jianqing
OPTICAL MATERIALS EXPRESS, 2015, 5 (03): : 462 - 468
[39] Preparation and properties of high refractive index ZrO2 nano-hybrid materials
Yao, Bolong
Hu, Xucan
Liu, Jiacheng
Chen, Kun
Liu, Jing
MATERIALS LETTERS, 2020, 261
[40] Preparation and properties of high refractive index UV-cured titanium hybrid optical materials
Hu, Xucan
Yao, Bolong
Liu, Jing
Liu, Jiacheng
Chen, Kun
Yan, Meng
Wang, Likui
MATERIALS LETTERS, 2020, 265

← 1 2 3 4 5 →