Thiol-Ene Click Chemistry

被引：3410
|
作者：
Hoyle, Charles E. [2 ]
Bowman, Christopher N. [1 ]
机构：
[1] Univ Colorado, Dept Chem & Biochem Engn, Boulder, CO 80309 USA
[2] Univ So Mississippi, Sch Polymers & High Performance Mat, Hattiesburg, MS 39406 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 09期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
click chemistry; Michael additions; polymerization; synthesis design; thiol-ene reaction; DISPERSED LIQUID-CRYSTAL; METHACRYLATE TERNARY-SYSTEMS; SELECTIVE CONJUGATE ADDITION; FREE-RADICAL ADDITION; POLYMERIZATION KINETICS; MECHANICAL-PROPERTIES; SURFACE MODIFICATION; DIBLOCK COPOLYMERS; NETWORK FORMATION; BLOCK-COPOLYMERS;
D O I：
10.1002/anie.200903924
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
"Chemical Equation Presented" Click and easy: The radical thiol-ene reaction (see scheme) fulfills all the criteria for being a click reaction, and it has a unique potential for applications in polymer science and molecular synthesis. Particular advantages are simplicity, high yields and conversions, high reaction rates, and the possibility of photoinitiation. © 2010 Wlley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1540 / 1573
页数：34
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