Anionic effects on Raman OD stretching spectra for alcoholic LiX solutions (X = Cl-, Br-, I-, ClO4-, NO3-, and CH3COO-)

被引：16
|
作者：
Hidaka, F [1 ]
Yoshimura, Y [1 ]
Kanno, H [1 ]
机构：
[1] Natl Def Acad, Dept Appl Chem, Kanagawa 2398686, Japan
来源：
JOURNAL OF SOLUTION CHEMISTRY | 2003年 / 32卷 / 03期
关键词：
alcoholic lithium salt solutions; anionic effect; Raman spectra; OD stretching vibration; glassy state;
D O I：
10.1023/A:1022986301621
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Raman OD stretching spectra of alcoholic LiX (X = Cl-, Br-, I-, ClO4-, NO3-, and CH3COO-) solutions ( alcohols D methanol and ethanol) were measured in the liquid state at room temperature and in the glassy state at liquid nitrogen temperature. The effects of the anions on the Raman OD stretching spectra in these alcoholic solutions are investigated and the structural changes of the solutions are discussed. It is shown that the structure-breaking effects of anions on the intrinsic alcoholic structure increase in the order: Cl- < Br- < I- < ClO4-. From spectral changes, it seems that CH3COOLi exerts little effect on the liquid structure of the alcohol.
引用
收藏
页码：239 / 251
页数：13
相关论文
共 50 条
  • [41] Structural analysis of dehydrated gibbsite-based layered double hydroxides Li-Al-X (X = F-, Cl-, Br-, I-, OH-, NO3-, CO32-, and SO42-) by DFT calculations
    Barbosa, Anna Carolina de A.
    Fonseca, Carla G.
    Wypych, Fernando
    Leitao, Alexandre A.
    NEW JOURNAL OF CHEMISTRY, 2020, 44 (24) : 10137 - 10145
  • [42] Low-dimensional compounds containing cyanido groups. XXIX. Crystal structures, spectral and magnetic properties of five [Cu(L)2X]C(CN)3 complexes (L=2,2'-bipyridine or 1,10-phenanthroline; X = Cl-, Br- or CH3COO-)
    Petrovic, Katarina
    Potocnak, Ivan
    Raczova, Katarina
    Cizmar, Erik
    Petrovic, Marian
    TRANSITION METAL CHEMISTRY, 2015, 40 (05) : 541 - 553
  • [43] Temperature dependent emission of hexarhenium(III) clusters [Re6(μ3-S)8X6]4- (X = Cl-, Br-, and I-):: Analysis by four excited triplet-state sublevels
    Kitamura, N
    Ueda, Y
    Ishizaka, S
    Yamada, K
    Aniya, M
    Sasaki, Y
    INORGANIC CHEMISTRY, 2005, 44 (18) : 6308 - 6313
  • [44] Theoretical study on the stability of the complexes A•••BX3 [A = CH3NH3+, NH2CHNH2+, NH2CHOH+; B = Sn2+, Pb2+; X = F-, Cl-, Br-, I-]
    Wang, Mengmeng
    Li, Wei
    Lu, Fangchao
    Ding, Xunlei
    JOURNAL OF MOLECULAR MODELING, 2020, 26 (03)
  • [45] Synthesis, characterization, and ion exchange properties of hydrotalcite Mg6Al2(OH)16(A)x(A′)2-x•4H2O (A, A′ = Cl-, Br, I-, and NO3-, 2≥x≥0) derivatives
    Bontchev, RP
    Liu, S
    Krumhansl, JL
    Voigt, J
    Nenoff, TM
    CHEMISTRY OF MATERIALS, 2003, 15 (19) : 3669 - 3675
  • [46] ION SENSITIVE ELECTRODES - NEW ELECTROCHEMICAL SENSORS FOR F-, CL-, BR-, I-, S--, CLO4(-) NO3(-), BF4(-), AG+, CU++, CA++, ZN++, ME++ IONS
    CAMMANN, K
    MESSTECHNIK, 1971, 79 (03): : 79 - &
  • [47] On the halide aggregation into the [Au4(PPh3)4]4+ cluster core. Insights from structural, optical and interaction energy analysis in [(Ph3PAu)4X2]2+ and [(Ph3PAu)4X]3+ species (X = Cl-, Br-, I-)
    Guajardo-Maturana, Raul
    Rodriguez-Kessler, Peter. L.
    Munoz-Castro, Alvaro
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2024, 26 (27) : 18828 - 18836
  • [48] Crystal structures, spectro-structural correlation and structural pathways of eight [Cu(dpyam)2(NCO)][Y] complexes (dpyam=di-2-pyridylamine), Y = Br-, CF3SO3-, BF4- • dpyam, Cl- • 4H2O, NO3-, PF6-, ClO4- and BPh4-
    Youngme, Sujittra
    Phatchimkun, Jaturong
    Suksangpanya, Unchulee
    Pakawatchai, Chaveng
    Chaichit, Narongsak
    Kongsaeree, Palangpon
    Krzystek, Jurek
    Murphy, Brian
    POLYHEDRON, 2007, 26 (04) : 871 - 882
  • [49] CORRELATION BETWEEN STRUCTURAL AND ELECTRICAL-PROPERTIES IN (1-X) AGPO3.XMX2 GLASSES (M = PB2+, HG2+ X = I-, BR-, CL-) FROM RAMAN-SPECTROSCOPY AND IONIC-CONDUCTIVITY MEASUREMENTS
    MALUGANI, JP
    MERCIER, R
    TACHEZ, M
    SOLID STATE IONICS, 1986, 21 (02) : 131 - 138
  • [50] Effect of lattice anions on the ligand substitution reaction of tris-(1,10-phenanthroline)metal(II) Complexes: [M(phen)3]SO4 and [M(phen)3]X2 (M: Fe(II), Co(II), Ni(II); X: Cl-, Br-, I-)
    Yamasaki, Shoji
    Fujiwara, Terufumi
    Yamamoto, Yuroku
    Bulletin of the Chemical Society of Japan, 1987, 60 (07): : 2565 - 2571
12345