Light-Responsive (Supra)Molecular Architectures: Recent Advances

被引:37
|
作者
Baroncini, Massimo [1 ,2 ]
Groppi, Jessica [1 ,2 ]
Corra, Stefano [1 ,2 ]
Silvi, Serena [3 ]
Credi, Alberto [1 ,2 ]
机构
[1] Univ Bologna, Dipartimento Sci & Tecnol Agroalimentari, Clan Ctr Light Activated Nanostruct, Via Gobetti 101, I-40129 Bologna, Italy
[2] CNR, Ist ISOF, Via Gobetti 101, I-40129 Bologna, Italy
[3] Univ Bologna, Dipartimento Chim G Ciamician, Via Selmi 2, I-40126 Bologna, Italy
基金
欧盟地平线“2020”; 欧洲研究理事会;
关键词
azobenzene photochromes; light actuators; light-responsive chemical systems; molecular architectures; molecular machines; photochromic compounds; photoswitchable molecular materials; MOLECULAR MACHINES; AZOBENZENE; SWITCHES; NANOFIBERS; CRYSTALS; ROTAXANE; CIS; PHOTOISOMERIZATION; PHOTOCHROMISM; DERIVATIVES;
D O I
10.1002/adom.201900392
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The development and investigation of (supra)molecular-based architectures characterized by light-activated functionalities is a highly relevant topic of chemical research. The interest on photo-controlled systems arises not only from their potential applications in different fields of technology but also from their scientific significance related to the understanding of light-matter interactions at the nanoscale. Indeed, light is a peculiar and unique tool as it can be conveniently applied to supply the energy required to affect and operate a system and, at the same time, to probe its state and investigate its transformations. Some basic aspects of light-induced processes in (supra)molecular architectures are discussed here in the frame of their use to implement novel functionalities in nanostructured systems and materials. In this perspective, a few recent examples from our own work will be illustrated which are meant to provide an overview of the current directions in this highly cross-disciplinary field of research.
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页数:16
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