EPDM Rubber with hexagonal Boron Nitride: A Thermal Neutron Shielding Composite

被引:25
|
作者
Gungor, A. [1 ]
Akbay, I. K. [1 ]
Ozdemir, T. [1 ]
机构
[1] Mersin Univ, Chem Engn Dept, TR-33343 Yenisehir, Mersin, Turkey
关键词
Ethylene propylene diene termonomer (EPDM); Hexagonal boron nitride (hBN); Rubber; Radiation; Neutron shielding; GAMMA; PARAMETERS;
D O I
10.1016/j.radphyschem.2019.108391
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Boron and boron-based materials are highly effective for thermal neutron shielding and a material with high hydrogen content is a good choice for neutron shielding. Hexagonal boron nitride (hBN) could be used as a thermal neutron shielding material thanks to its high boron content. On the other hand, EPDM, which has high hydrogen content, has relatively economical price compared to other commercial rubbers. In this study, the EPDM/hBN composite was developed for the purpose of thermal neutron shielding. Kinetic analysis showed that the non-autocatalytic reaction was the main reaction type leading the vulcanization process. It was seen from the mechanical tests, the increase in hBN content has changed the nature of the composite. Thermal analysis showed that the addition of hBN content improved thermal stability. Thermal neutron attenuation tests showed that the EPDM/hBN samples attenuated the neutron radiation up to 61.5%. The theoretical neutron shielding tests showed that hBN20 is the best sample for neutron absorption. The HVL value was calculated as 1.08 cm for hBN20 sample. The results showed that the prepared EPDM/hBN composite is a good neutron shielding material.
引用
收藏
页数:8
相关论文
共 50 条
  • [31] Improvement of thermal propagation in carbon fiber/thermoplastic composite with hexagonal boron nitride powder
    Shimamoto, Daisuke
    Tominaga, Yuichi
    Imai, Yusuke
    Hotta, Yuji
    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2015, 123 (1443) : 1055 - 1058
  • [32] Hexagonal boron nitride composite photocatalysts for hydrogen production
    Li, Xuan
    Zhang, Jing
    Zhang, Shijie
    Xu, Shasha
    Wu, Xiaoge
    Chang, Jingcai
    He, Zuoli
    JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 864
  • [33] Hexagonal boron nitride composite photocatalysts for hydrogen production
    Li, Xuan
    Zhang, Jing
    Zhang, Shijie
    Xu, Shasha
    Wu, Xiaoge
    Chang, Jingcai
    He, Zuoli
    Wu, Xiaoge (xgwu@yzu.edu.cn); He, Zuoli (zlhe@sdu.edu.cn), 1600, Elsevier Ltd (864):
  • [34] Synthesis and characterization of polyimide/hexagonal boron nitride composite
    Kizilkaya, Canan
    Mulazim, Yusuf
    Kahraman, Memet Vezir
    Apohan, Nilhan Kayaman
    Gungor, Atilla
    JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 124 (01) : 706 - 712
  • [35] Designing a boron nitride polyethylene composite for shielding neutrons
    Vira, A. D.
    Mone, E. M.
    Ryan, E. A.
    Connolly, P. T.
    Smith, K.
    Roecker, C. D.
    Mesick, K. E.
    Orlando, T. M.
    Jiang, Z.
    First, P. N.
    APL MATERIALS, 2023, 11 (10)
  • [36] Growth of hexagonal boron nitride on (111) Si for deep UV photonics and thermal neutron detection
    Ahmed, K.
    Dahal, R.
    Weltz, A.
    Lu, J. -Q.
    Danon, Y.
    Bhat, I. B.
    APPLIED PHYSICS LETTERS, 2016, 109 (11)
  • [37] Growth and device processing of hexagonal boron nitride epilayers for thermal neutron and deep ultraviolet detectors
    Doan, T. C.
    Li, J.
    Lin, J. Y.
    Jiang, H. X.
    AIP ADVANCES, 2016, 6 (07):
  • [38] Neutron damage of hexagonal boron nitride: h-BN
    Cataldo, Franco
    Iglesias-Groth, Susana
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2017, 313 (01) : 261 - 271
  • [39] Neutron damage of hexagonal boron nitride: h-BN
    Franco Cataldo
    Susana Iglesias-Groth
    Journal of Radioanalytical and Nuclear Chemistry, 2017, 313 : 261 - 271
  • [40] Response of alpha particles in hexagonal boron nitride neutron detectors
    Doan, T. C.
    Li, J.
    Lin, J. Y.
    Jiang, H. X.
    APPLIED PHYSICS LETTERS, 2017, 110 (21)