EPDM Rubber with hexagonal Boron Nitride: A Thermal Neutron Shielding Composite

被引:25
|
作者
Gungor, A. [1 ]
Akbay, I. K. [1 ]
Ozdemir, T. [1 ]
机构
[1] Mersin Univ, Chem Engn Dept, TR-33343 Yenisehir, Mersin, Turkey
关键词
Ethylene propylene diene termonomer (EPDM); Hexagonal boron nitride (hBN); Rubber; Radiation; Neutron shielding; GAMMA; PARAMETERS;
D O I
10.1016/j.radphyschem.2019.108391
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Boron and boron-based materials are highly effective for thermal neutron shielding and a material with high hydrogen content is a good choice for neutron shielding. Hexagonal boron nitride (hBN) could be used as a thermal neutron shielding material thanks to its high boron content. On the other hand, EPDM, which has high hydrogen content, has relatively economical price compared to other commercial rubbers. In this study, the EPDM/hBN composite was developed for the purpose of thermal neutron shielding. Kinetic analysis showed that the non-autocatalytic reaction was the main reaction type leading the vulcanization process. It was seen from the mechanical tests, the increase in hBN content has changed the nature of the composite. Thermal analysis showed that the addition of hBN content improved thermal stability. Thermal neutron attenuation tests showed that the EPDM/hBN samples attenuated the neutron radiation up to 61.5%. The theoretical neutron shielding tests showed that hBN20 is the best sample for neutron absorption. The HVL value was calculated as 1.08 cm for hBN20 sample. The results showed that the prepared EPDM/hBN composite is a good neutron shielding material.
引用
收藏
页数:8
相关论文
共 50 条
  • [1] Hexagonal boron nitride and polydimethylsiloxane: A ceramic rubber composite material for neutron shielding
    Ozdemir, Tonguc
    Yilmaz, Seda Nur
    RADIATION PHYSICS AND CHEMISTRY, 2018, 152 : 93 - 99
  • [2] Flexible neutron shielding composite material of EPDM rubber with boron trioxide: Mechanical, thermal investigations and neutron shielding tests
    Ozdemir, T.
    Gungor, A.
    Reyhancan, I. A.
    RADIATION PHYSICS AND CHEMISTRY, 2017, 131 : 7 - 12
  • [3] Multilayer polyethylene/hexagonal boron nitride composites showing high neutron shielding efficiency and thermal conductivity
    Shang, Ying
    Yang, Gui
    Su, Fengmei
    Feng, Yuezhan
    Ji, Youxin
    Liu, Dong
    Yin, Rui
    Liu, Chuntai
    Shen, Changyu
    COMPOSITES COMMUNICATIONS, 2020, 19 : 147 - 153
  • [4] The effects of the hexagonal boron nitride nanoflake properties on the thermal conductivity of hexagonal boron nitride nanoflake/silicone rubber composites
    Zhong, Bo
    Zou, Jiaxin
    An, Lulu
    Ji, Chengyu
    Huang, Xiaoxiao
    Liu, Wei
    Yu, Yuanlie
    Wang, Huatao
    Wen, Guangwu
    Zhao, Kun
    Lin, Xuesong
    COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2019, 127
  • [5] Thermal neutron detectors based on hexagonal boron nitride epilayers
    Doan, T. C.
    Marty, A.
    Li, J.
    Lin, J. Y.
    Jiang, H. X.
    HARD X-RAY, GAMMA-RAY, AND NEUTRON DETECTOR PHYSICS XVIII, 2016, 9968
  • [6] Neutron shielding of EPDM rubber with boric acid: Mechanical, thermal properties and neutron absorption tests
    Ozdemir, T.
    Akbay, I. K.
    Uzun, H.
    Reyhancan, I. A.
    PROGRESS IN NUCLEAR ENERGY, 2016, 89 : 102 - 109
  • [7] Multiwalled boron nitride microtubes (BNMTs) shielding in thermal neutron absorbing
    Arslan, K.
    Seval, H. K.
    Murathan, O. F.
    Soysal, K.
    RADIATION EFFECTS AND DEFECTS IN SOLIDS, 2018, 173 (7-8): : 555 - 566
  • [8] High loading boron nitride chemically bonded with silicone rubber to enhance thermal neutron shielding and flexibility of polymer nanocomposites
    Li, Jia-Le
    Zhang, Quan-Ping
    Liu, Xue
    Chen, Rui-Chao
    Xu, Wei-Di
    Sun, Nan
    Li, Yin-Tao
    Yang, Wen-Bin
    Xu, Dui-Gong
    Zhou, Yuan-Lin
    JOURNAL OF APPLIED POLYMER SCIENCE, 2021, 138 (31)
  • [9] Few-layer hexagonal boron nitride / 3D printable polyurethane composite for neutron radiation shielding applications
    Knott, Jonathan C.
    Khakbaz, Hadis
    Allen, Jackson
    Wu, Liang
    Mole, Richard A.
    Baldwin, Christopher
    Nelson, Andrew
    Sokolova, Anna
    Beirne, Stephen
    Innis, Peter C.
    Frost, Dillon G.
    Cortie, David
    Rule, Kirrily C.
    COMPOSITES SCIENCE AND TECHNOLOGY, 2023, 233
  • [10] High-density polyethylene/EPDM rubber blend composites of boron compounds for neutron shielding application
    Abdulrahman, Sajith Thottathil
    Patanair, Bindu
    Vasukuttan, Vineeth Puthuparampil
    Thomas, Sabu
    Cadel, Emmanuel
    Cuvilly, Fabien
    Saiter-Fourcin, Allisson
    Ahmad, Zakiah
    Jaroszewski, Maciej
    Strankowski, Michal
    Laroze, David
    EXPRESS POLYMER LETTERS, 2022, 16 (06): : 558 - 572