Helical chirality in pentacoordinate zinc complexes -: Selective access to both pseudoenantiomers with one ligand configuration

被引：25

作者：

Seitz, M

Stempfhuber, S

Zabel, M

Schütz, M

Reiser, O ^{[1
]}

机构：

[1] Univ Regensburg, Inst Organ Chem, Univ Str 31, D-93053 Regensburg, Germany

[2] Univ Regensburg, Inst Anorgan Chem, D-93053 Regensburg, Germany

[3] Univ Stuttgart, Inst Theoret Chem, D-70569 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 02期

关键词：

bisoxazoline ligands; coordination chemistry; helical chirality; stereogenic metal centers; zinc;

D O I：

10.1002/anie.200460843

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Δ 2 or Λ 2 that is the question! Depending on the heteroatom X, the pentadentate bis(oxazoline) ligand will fold around a zinc(II) ion exclusively in the Δ 2 or Λ 2 configuration, both in solution and in the solid state.

引用

页码：242 / 245

页数：4

共 43 条

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