Hypervalent Iodine as a Terminal Oxidant in Wacker-Type Oxidation of Terminal Olefins to Methyl Ketones

被引：53
|
作者：
Chaudhari, Dipali A. [1 ]
Fernandes, Rodney A. [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 81卷 / 05期
关键词：
SUPERCRITICAL CARBON-DIOXIDE; DESS-MARTIN PERIODINANE; PALLADIUM-CATALYZED OXIDATION; PROTECTED ALLYLIC AMINES; SELECTIVE OXIDATION; AEROBIC OXIDATION; SECONDARY ALCOHOLS; MOLECULAR-OXYGEN; SOLE OXIDANT; EFFICIENT;
D O I：
10.1021/acs.joc.6b00137
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mimic of the Wacker process for C=O bond formation in terminal olefins can be initiated by a combination of the Pd(II) and hypervalent iodine reagent, Dess-Martin periodinane to generate methyl ketones. This operationally simple and scalable method offers Markovnikov selectivity, has good functional group compatibility, and is mild and high yielding.
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页码：2113 / 2121
页数：9
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