Structural control of ferromagnetic interactions in nickel(II) complexes based on a tetradentate biradical

被引:49
|
作者
Romero, FM
Luneau, D
Ziessel, R
机构
[1] Ecole Chim Polymers & Mat, UPRES A 7008, Lab Chim Elect & Photon Mol, F-67008 Strasbourg, France
[2] CEA Grenoble, Dept Rech Fondamentale Mat Condensee, Serv Chim Inorgan & Biol, Lab Chim Coordinat,URA CNRS 1194, F-38054 Grenoble, France
关键词
D O I
10.1039/a707350j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Complexation of a bipyridine-based nitronyl nitroxide biradical with nickel(II) affords two complexes that differ by the nature of one axial ligand and by their magnetic behaviour: in both cases ferromagnetic interactions between high-spin nickel(II) and the radicals are observed.
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页码:551 / 552
页数:2
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