Microwave assisted synthesis of novel zinc(II) phthalocyanines bearing 1,3-diazido-2-propanoxy functional groups and investigation of their photochemical properties

被引：9
|
作者：
Sari, Sait [1 ]
Durmus, Mahmut [2 ]
Bulut, Mustafa [1 ]
机构：
[1] Marmara Univ, Dept Chem, TR-34722 Istanbul, Turkey
[2] Gebze Tech Univ, Dept Chem, POB 141, TR-41400 Gebze, Kocaeli, Turkey
来源：
TETRAHEDRON LETTERS | 2016年 / 57卷 / 10期
关键词：
Phthalocyanine; Zinc; Azide; Singlet oxygen; Microwave; PHOTOSENSITIZED SINGLET OXYGEN; BEHAVIOR; DESIGN;
D O I：
10.1016/j.tetlet.2016.01.100
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this study, three novel phthalonitriles (1, 2 and 3) bearing 1,3-diazido-2-propanoxy substituents were synthesized by conventional methods and their zinc(II) phthalocyanine complexes (4, 5 and 6) were synthesized by microwave irradiation because of the low stability of the azide groups at a high temperature under conventional heating. All novel compounds were fully characterized by elemental analyses, FT-IR, H-1 NMR, UV-Vis, and MALDI-TOF spectral data. Furthermore, spectroscopic and photochemical properties such as singlet oxygen generation and the photostability of these zinc(II) phthalocyanines were investigated in DMSO. (C) 2016 Elsevier Ltd. All rights reserved.
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页码：1124 / 1128
页数：5
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