One-step preparation of single-layered graphene quantum dots for the detection of Fe3+

被引:21
|
作者
Wang, Haogiang [1 ]
Wu, Xingxing [1 ]
Dong, Weilong [2 ]
Lee, Shern-Long [3 ]
Yuan, Qunhui [1 ]
Gan, Wei [4 ]
机构
[1] Harbin Inst Technol Shenzhen, State Key Lab Adv Welding & Joining, Sch Mat Sci & Engn, Shenzhen 518055, Guangdong, Peoples R China
[2] Shenzhen Univ, Coll Optoelect Engn, Shenzhen 518055, Guangdong, Peoples R China
[3] Shenzhen Univ, Inst Adv Study, Shenzhen 518055, Guangdong, Peoples R China
[4] Harbin Inst Technol Shenzhen, Sch Sci, Shenzhen 518055, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Single-layered graphene quantum dots; One-step preparation; beta-cydodextrin; Fluorescence sensing; Ferric ion; DOPED CARBON DOTS; CYCLODEXTRIN FUNCTIONALIZED GRAPHENE; ELECTROCHEMICAL SENSOR; GREEN SYNTHESIS; NITROGEN; MERCURY; PROBE; IONS;
D O I
10.1016/j.saa.2019.117626
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Single-layer graphene quantum dots are highly desirable while their facile and controllable preparations remain challenging. Herein, single-layered graphene quantum dots (sl-GQDs) were developed via a facile one-step hydrothermal synthesis, with citric add and beta-cyclodextrin (CD) as starting materials. The sl-GQDs decorated with CD molecules emit green fluorescence with a quantum yield of 5.34%, and exhibit a good response exclusively to ferric ions for their structural oxygenous groups. The linear range of the proposed sensor for ferric ions was found in a wide concentration range of 0-85 mu M. The detection limit is about 0.26 mu M. The sl-GQDs based sensing platform also demonstrates its feasibility in real water sample analysis with recoveries of 93.8%-101.5%. (C) 2019 Elsevier B.V. All rights reserved.
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页数:7
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