Asymmetric Organocatalysis in Deep Eutectic Solvents

被引：40

作者：

Alonso, Diego A. ^{[1
,2
]}

Burlingham, Sarah-Jayne ^{[1
,2
]}

Chinchilla, Rafael ^{[1
,2
]}

Guillena, Gabriela ^{[1
,2
]}

Ramon, Diego J. ^{[1
,2
]}

Tiecco, Matteo ^{[3
]}

机构：

[1] Alicante Univ, Dept Organ Chem, POB 99, Alicante 03080, Spain

[2] Alicante Univ, Inst Organ Synth, POB 99, Alicante 03080, Spain

[3] Univ Perugia, Dept Chem Biol & Biotechnol, Via Elce Sotto 8, I-06124 Perugia, Italy

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 2021卷 / 29期

关键词：

Active solvents; Asymmetric organocatalysis; Deep eutectic solvents; Enantioselectivity; Green chemistry; CHIRAL IONIC LIQUIDS; 1,3-DICARBONYL COMPOUNDS; CONJUGATE ADDITION; MICHAEL ADDITION; REACTION MEDIA; MALEIMIDES; 2-AMINOBENZIMIDAZOLES; ALDEHYDES; MIXTURES;

D O I：

10.1002/ejoc.202100385

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The recent advances in asymmetric organocatalysis using eutectic mixtures as a reaction medium are revised in this mini-review. In addition, the first enantioselective transformations using chiral eutectic solvents, which play the role of a green medium and organocatalyst, are described. In this minireview we intend to deepen not only in the synthetic aspects of asymmetric organocatalysis in eutectic mixtures, but also in the fundamental issues that seem to be essential for a successful development of this promising, and at the same time challenging, methodology.

引用

页码：4065 / 4071

页数：7

共 50 条

[21] Green and sustainable solvents of the future: Deep eutectic solvents
Prabhune, Aditi
Dey, Ranjan
JOURNAL OF MOLECULAR LIQUIDS, 2023, 379
[22] Deep Eutectic Solvents as an Alternate to Other Harmful Solvents
Sekharan, T. Raja
Chandira, R. Margret
Tamilvanan, Shunmugaperumal
Rajesh, S. C.
Venkateswarlu, B. S.
BIOINTERFACE RESEARCH IN APPLIED CHEMISTRY, 2022, 12 (01): : 847 - 860
[23] Gas solubilities in deep eutectic solvents
Yizhak Marcus
Monatshefte für Chemie - Chemical Monthly, 2018, 149 : 211 - 217
[24] Water absorption by deep eutectic solvents
Chen, Yu
Yu, Dongkun
Chen, Wenjun
Fu, Li
Mu, Tiancheng
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2019, 21 (05) : 2601 - 2610
[25] Electrified interfaces of deep eutectic solvents
Costa, Renata
Brandao, Ana T. S. C.
Pereira, Carlos M.
Silva, A. Fernando
ELECTROCHIMICA ACTA, 2023, 461
[26] Intrinsically Electrochromic Deep Eutectic Solvents
Cruz, Hugo
Jordao, Noemi
Dionisio, Madalena
Pina, Fernando
Branco, Luis C.
CHEMISTRYSELECT, 2019, 4 (04): : 1530 - 1534
[27] Deep Eutectic Solvents for Starch Treatment
Skowronska, Dorota
Wilpiszewska, Katarzyna
POLYMERS, 2022, 14 (02)
[28] Deep Eutectic Solvents to Organic Synthesis
Wang Ailing
Zheng Xueliang
Zhao Zhuangzhi
Li Changping
Zheng Xuefang
PROGRESS IN CHEMISTRY, 2014, 26 (05) : 784 - 795
[29] Deep Eutectic Solvents for Biotechnology Applications
Morozova, Olga V.
Vasil'eva, Irina S.
Shumakovich, Galina P.
Zaitseva, Elena A.
Yaropolov, Alexander I.
BIOCHEMISTRY-MOSCOW, 2023, 88 (SUPPL 1) : S150 - S175
[30] Are deep eutectic solvents benign or toxic?
Hayyan, Maan
Hashim, Mohd Ali
Hayyan, Adeeb
Al-Saadi, Mohammed A.
AlNashef, Inas M.
Mirghani, Mohamed E. S.
Saheed, Olorunnisola Kola
CHEMOSPHERE, 2013, 90 (07) : 2193 - 2195

← 1 2 3 4 5 →