Phase equilibrium in the PbSnS2-PbSb2S4 system

被引：2
|
作者：
Mamedov, Sh G. [1 ]
Bakhtiyarly, I. B. [1 ]
Kurbanov, G. R. [1 ]
机构：
[1] Natl Acad Sci Azerbaijan, Nagiev Inst Chem Problems, Baku, Azerbaijan
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 04期
关键词：
Component Ratio; Chemical Transport; Single Crystal Growth; Lead Sulfate; Melting Compound;
D O I：
10.1134/S0036023610040212
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The PbSnS2-PbSb2S4 system was studied by physicochemical methods, and its phase diagram was plotted. The system is quasi-binary; solid solutions regions based on PbSnS2 (6 mol % PbSb2S4) and PbSb2S4 (12 mol % PbSnS2) were revealed. At a component ratio of 1: 1, a congruently melting compound Pb2SnSb2S6 is formed. Pb2SnSb2S6 single crystals were obtained by chemical transport. The unit cell parameters of Pb2SnSb2S6, which crystallizes in orthorhombic system, were determined: a = 15.22 , b = 10.68 , c = 3.90 .
引用
收藏
页码：626 / 628
页数：3
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