A five-coordinate chromium alkyl complex stabilised by salicylaldiminato ligands

被引：117

作者：

Gibson, VC ^{[1
]}

Mastroianni, S ^{[1
]}

Newton, C ^{[1
]}

Redshaw, C ^{[1
]}

Solan, GA ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 13期

关键词：

D O I：

10.1039/b002631j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The five-coordinate bis(salicylaldiminato)chromium(III) complex [3,5-(t-Bu)(2)(O)C6H2CHN(2,6-i-Pr2C6H3)](2)CrCl (2) reacts with triethylaluminium in THF at room temperature to give the air sensitive ethyl species [3,5-(t-Bu)(2)(O)C6H2CHN(2,6-i-Pr2C6H3)](2)CrEt (3); in the presence of aluminium activators, 2 and 3 are moderately active ethylene polymerisation catalysts.

引用

页码：1969 / 1971

页数：3

共 50 条

[31] Synthesis and Structural Characterization of Five-Coordinate Aluminum Complexes Containing Diarylamido Diphosphine Ligands
Lee, Pei-Ying
Liang, Lan-Chang
INORGANIC CHEMISTRY, 2009, 48 (12) : 5480 - 5487
[32] Antitumor properties of five-coordinate gold(III) complexes bearing substituted polypyridyl ligands
Sanghvi, Chinar D.
Olsen, Pauline M.
Elix, Catherine
Peng, Shifang
Wang, Dongsheng
Chen, Zhuo
Shin, Dong M.
Hardcastle, Kenneth I.
MacBeth, Cora E.
Eichler, Jack F.
JOURNAL OF INORGANIC BIOCHEMISTRY, 2013, 128 : 68 - 76
[33] Distinct optoelectronic properties of four-coordinate and five-coordinate Zn(II) complexes with chiral polypyridine ligands
Zhang, Xiao-Peng
Qi, Xiao-Wei
Zhang, Da-Shuai
Zhu, Lin-Hua
Wang, Xiang-Hui
Shi, Zai-Feng
Lin, Qiang
POLYHEDRON, 2017, 126 : 111 - 119
[34] Reversible binding of water, methanol, and ethanol to a five-coordinate ruthenium(II) complex
Ma, Erin S. F.
Patrick, Brian O.
James, Brian R.
DALTON TRANSACTIONS, 2013, 42 (12) : 4291 - 4298
[35] A five-coordinate bis(p-bromophenyl-salicylaldimino)chloroiron(III) complex
Elerman, Y
Paulus, H
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 1971 - 1973
[36] Five-coordinate complex formation and luminescence quenching study of copper(II) porphyrins
Szintay, G
Horváth, A
INORGANICA CHIMICA ACTA, 2001, 324 (1-2) : 278 - 285
[37] Spin modulation and electrochemical behavior of a five-coordinate cobalt(III) salen complex
Buchwald, James R.
Kal, Subhadeep
Civic, Marissa R.
deJoode, Ian M.
Filatov, Alexander S.
Dinolfo, Peter H.
JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (11-13) : 1695 - 1708
[38] Trapping five-coordinate platinum(IV) intermediates
Shaw, Paul A.
Phillips, Jessica M.
Clarkson, Guy J.
Rourke, Jonathan P.
DALTON TRANSACTIONS, 2016, 45 (28) : 11397 - 11406
[39] Total Spontaneous Resolution of Five-Coordinate Complexes
Lennartson, Anders
Hakansson, Mikael
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (32) : 5869 - 5871
[40] Synthesis and characterization of five-coordinate gallium and indium complexes stabilized by tridentate, substituted pyrrole ligands
Kuo, PC
Huang, JH
Hung, CH
Lee, GH
Peng, SM
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (07) : 1440 - 1444

← 1 2 3 4 5 →