Stability of large-area molecular junctions

被引:39
|
作者
Akkerman, Hylke B. [1 ]
Kronemeijer, Auke J. [1 ]
Harkema, Jan [1 ]
van Hal, Paul A. [2 ]
Smits, Edsger C. P. [1 ,2 ]
de Leeuw, Dago M. [1 ,2 ]
Blom, Paul W. M. [1 ]
机构
[1] Univ Groningen, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands
[2] Philips Res Labs, NL-5656AE Eindhoven, Netherlands
关键词
Molecular electronics; Molecular devices; Self-assembled monolayers; Stability; Alkanedithiols; SELF-ASSEMBLED MONOLAYERS; ALKYL THIOL MONOLAYERS; SPECTROSCOPY; ELECTRONICS; METALS;
D O I
10.1016/j.orgel.2009.09.013
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The stability of molecular junctions is crucial for any application of molecular electronics. Degradation of molecular junctions when exposed to ambient conditions is regularly observed. In this report the stability of large-area molecular junctions under ambient conditions for more than two years is presented. Furthermore, the thermal stability of molecular junctions at elevated temperatures is investigated. A transition temperature at 50 degrees C was observed for molecular junctions based on self-assembled monolayers of alkanedithiols, above which the resistance decreases exponentially with temperature. This transition temperature limits the process window during fabrication and the temperature window during operation. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:146 / 149
页数:4
相关论文
共 50 条
  • [31] Molecular excitation by large-area ultrashort pulses
    Paloviita, A
    Suominen, KA
    PHYSICAL REVIEW A, 1997, 55 (04): : 3007 - 3013
  • [32] Influence of bias-induced barrier height lowering on charge tunneling in large-area molecular junctions
    Hong, Seock-Hyeon
    Im, Kyungjin
    Song, Hyunwook
    JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2022, 81 (01) : 49 - 53
  • [33] Influence of bias-induced barrier height lowering on charge tunneling in large-area molecular junctions
    Seock-Hyeon Hong
    Kyungjin Im
    Hyunwook Song
    Journal of the Korean Physical Society, 2022, 81 : 49 - 53
  • [34] Tunneling and thermoelectric characteristics of N-heterocyclic carbene-based large-area molecular junctions
    Kang, Seohyun
    Park, Sohyun
    Kang, Hungu
    Cho, Soo Jin
    Song, Hyunsun
    Yoon, Hyo Jae
    CHEMICAL COMMUNICATIONS, 2019, 55 (60) : 8780 - 8783
  • [35] HYSTERESIS IN RF-DRIVEN LARGE-AREA JOSEPHSON-JUNCTIONS
    OLSEN, OH
    SAMUELSEN, MR
    PHYSICAL REVIEW B, 1986, 34 (05): : 3510 - 3512
  • [36] Electrochemical fabrication of large-area Au/TiO2 junctions
    Tang, J
    White, M
    Stucky, GD
    McFarland, EW
    ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (06) : 497 - 501
  • [37] Large-Area Schottky Junctions between ZnO and Carbon Nanotube Fibres
    Monreal-Bernal, Alfonso
    Vilatela, Juan J.
    CHEMPLUSCHEM, 2018, 83 (04): : 285 - 293
  • [38] Stability, encapsulation and large-area fabrication of organic photovoltaics
    Song, Shan
    Lu, Jiaorong
    Ye, Weiyu
    Zhang, Bei
    Liu, Xuan
    Xing, Guichuan
    Zhang, Shiming
    SCIENCE CHINA-CHEMISTRY, 2021, 64 (09) : 1441 - 1459
  • [39] Stability, encapsulation and large-area fabrication of organic photovoltaics
    Shan Song
    Jiaorong Lu
    Weiyu Ye
    Bei Zhang
    Xuan Liu
    Guichuan Xing
    Shiming Zhang
    Science China(Chemistry), 2021, (09) : 1441 - 1459
  • [40] Stability, encapsulation and large-area fabrication of organic photovoltaics
    Shan Song
    Jiaorong Lu
    Weiyu Ye
    Bei Zhang
    Xuan Liu
    Guichuan Xing
    Shiming Zhang
    Science China(Chemistry), 2021, 64 (09) : 1441 - 1459