Carbon Monoxide (CO)- and Hydrogen-Driven, Vanadium-Catalyzed Deoxydehydration of Glycols

被引：42
|
作者：
Gopaladasu, Tirupathi V. [1 ]
Nicholas, Kenneth M. [1 ]
机构：
[1] Univ Oklahoma, Stephenson Life Sci Res Ctr, Dept Chem & Biochem, 101 Stephenson Pkwy, Norman, OK 73019 USA
来源：
ACS CATALYSIS | 2016年 / 6卷 / 03期
关键词：
deoxydehydration; glycol; oxo-vanadium; carbon monoxide; hydrogen; SULFITE-DRIVEN; CO OXIDATION; ALKENES; CONVERSION; COMPLEXES; ALCOHOL; POLYOLS; DIOLS; DEOXYGENATION; REDUCTION;
D O I：
10.1021/acscatal.5b02667
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Four oxo-vanadium complexes of the type Z(+)LVO(2)(-) (1-4) have been evaluated for activity as catalysts for the deoxydehydration (DODH) of glycols to olefins with various reductants. Among these, a new complex, [Bu4N]- (Salhyd)VO2 (4), is found to be uniquely effective for the DODH reaction using the practical reductants: hydrogen and carbon monoxide (CO).
引用
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页码：1901 / 1904
页数：4
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