Synthesis, crystal structure, and magnetic properties of an azido-bridged Mn(II) complex [C3H5NH3][Mn(N3)3]

被引：5

作者：

Qian, Kun ^{[1
]}

Xu, Yiyong ^{[2
]}

Wang, Zengtao ^{[1
]}

Yang, Jie ^{[1
]}

机构：

[1] Jiangxi Univ Tradit Chinese Med, Coll Pharm, Nanchang 330004, Jiangxi, Peoples R China

[2] Jiangxi Univ Tradit Chinese Med, Acad Adm, Nanchang 330004, Jiangxi, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2017年 / 72卷 / 06期

关键词：

antiferromagnetism; azido-bridged couple; coordination polymer; PHASE-TRANSITIONS; HYBRIDS (CNH2N+1NH3)(2)PBI4; PEROVSKITE ARCHITECTURE; ORGANIC FRAMEWORK; COMPOUND; DYNAMICS; ORDER;

D O I：

10.1515/znb-2016-0267

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new compound [C-3 H-5 NH3][Mn(N-3)(3)] has been synthesized, in which the Mn2+ ions are connected by the end-to-end azide anions to form the 3D architecture, while the C-3 H-5 NH3+ cations reside in the cavities of the Mn2+-N-3(-) network, forming rich N-H center dot center dot center dot N hydrogen bonds with the terminal N atoms of the azide anions. The complex has been characterized by IR spectroscopy, elemental analyses, and magnetic measurements. Magnetic susceptibility data indicate antiferromagnetic interaction among the Mn-II ions.

引用

页码：409 / 413

页数：5

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