Proton migration in -N...H...O- hydrogen-bonded complex of (Chloranilic acid) (1,2-Diazine)2 studied by dielectric response and infrared absorption spectra

被引：26

作者：

Suzuki, Hideaki

Mori, Hatsumi

Yamaura, Jun-ichi

Matsuda, Masaki

Tajima, Hiroyuki

Mochida, Tomoyuki

机构：

[1] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan

[2] Toho Univ, Dept Chem, Funabashi, Chiba 2748510, Japan

来源：

CHEMISTRY LETTERS | 2007年 / 36卷 / 03期

关键词：

D O I：

10.1246/cl.2007.402

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dielectric response by an intermolecular -(NHO)-H-...-O-...-proton transfer was observed around 120K for (Chloranilic acid) (1,2-Di azine)(2) [CA(1,2-DA)(2)]. This response, observed on the way of the migration from N-(HO)-O-... at 300K to O-(HN)-N-... below 90 K, was demonstrated by infrared absorption spectra and the temperature dependence of lattice constants.

引用

页码：402 / 403

页数：2

共 17 条

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