Self-assembly of 1,4-cis-polybutadiene and an aromatic host to fabricate nanostructured crystals by CH•••π interactions

被引：26

作者：

Bracco, Silvia ^{[1
]}

Comotti, Angiolina ^{[1
]}

Valsesia, Patrizia ^{[1
]}

Beretta, Mario ^{[1
]}

Sozzani, Piero ^{[1
]}

机构：

[1] Univ Milano Bicocca, Dept Mat Sci, Milan, Italy

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 08期

关键词：

SOLID-STATE NMR; MAS NMR; INCLUSION; POLYMER; NANOCOMPOSITES; NANOCHANNELS; PERHYDROTRIPHENYLENE; CONFORMATION; SPECTROSCOPY; DYNAMICS;

D O I：

10.1039/c002931a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembled supramolecular crystals fabricated by solvent-free mechanochemical treatments of a crystalline host and a rubbery polymer are stabilized by cooperative CH center dot center dot center dot pi interactions as revealed by H-1 fast-MAS and 2D solid state NMR.

引用

页码：2318 / 2321

页数：4