Kinetics, polymer molecular weights, and microstructure zirconocene-catalyzed 1-hexene polymerization

被引：0
|
作者：
Zhao, X [1 ]
Odian, G [1 ]
Rossi, A [1 ]
机构：
[1] CUNY Coll Staten Isl, Staten Isl, NY 10314 USA
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2000年 / 38卷 / 20期
关键词：
zirconocene; 1-hexene polymerization;
D O I：
10.1002/1099-0518(20001015)38:20<3802::AID-POLA110>3.0.CO;2-N
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
1-Hexene was polymerized by rac-(dimethylsilyl)bis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride catalyst and methylaluminoxane cocatalyst over the temperature range 0-100 degrees C. The polymerization rate, polymer molecular weight, and polymer microstructure (stereospecificity and regiospecificity) were studied as a function of the temperature and the concentrations of monomer, catalyst, and cocatalyst. (C) 2000 John Wiley & Sons, Inc.
引用
收藏
页码：3802 / 3811
页数：10
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