Born-Oppenheimer approximation near level crossing

被引:11
|
作者
Gordon, A [1 ]
Avron, JE [1 ]
机构
[1] Technion Israel Inst Technol, Dept Phys, IL-32000 Haifa, Israel
关键词
D O I
10.1103/PhysRevLett.85.34
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We consider rhs Born-Oppenheimer problem near conical intersection in two dimensions. For energies close to the crossing energy we describe the wave function near an isotropic crossing and show that it is related to generalized hypergeometric functions F-0(3). This function is to a conical intersection what the Airy function is to a classical turning point. As an application we calculate the anomalous Zeeman shift of vibrational levels near a crossing.
引用
收藏
页码:34 / 37
页数:4
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