1:1 and 2:1 charge-transfer complexes between aromatic hydrocarbons and dry titanium dioxide

被引：49

作者：

Seo, YS

Lee, C

Lee, KH

Yoon, KB ^{[1
]}

机构：

[1] Sogang Univ, Ctr Microstruct Assembly, Seoul 121742, South Korea

[2] Sogang Univ, Dept Chem, Seoul 121742, South Korea

[3] Wonkwang Univ, Dept Chem, Iksan 570749, Jeonbuk, South Korea

[4] Wonkwang Univ, Res Inst Basic Sci, Iksan 570749, Jeonbuk, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 06期

关键词：

arenes; charge transfer; physisorption; surface chemistry; titanium dioxide;

D O I：

10.1002/anie.200461972

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coloration of TiO2 upon contact with solutions of aromatic hydrocarbons is explained by the formation of 1:1 and 2:1 complexes (see picture) by physical adsorption. UV/Vis spectra and calculations indicate that these complexes are based on a charge-transfer interaction.

引用

页码：910 / 913

页数：4

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