Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride.: Support for a stepwise mechanism

被引：58
|
作者：
Samec, JSM [1 ]
Éll, AH [1 ]
Bäckvall, JE [1 ]
机构：
[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 23期
关键词：
D O I：
10.1039/b410698a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The negligible double kinetic deuterium isotope effect (k(HH)/ k(DD) = 1.05) in the reaction where [2,3,4,5-Ph-4(eta(5)-C4COH) Ru(CO)(2)H (2) transfers a hydride and a proton to N-phenyl-[1-(4-methoxyphenyl) ethylidene] amine (4) indicates that no bond to hydrogen is broken or formed in the rate-determining step.
引用
收藏
页码：2748 / 2749
页数：2
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