Palladium-catalyzed synthesis of aldehydes from aryl halides and tert-butyl isocyanide using formate salts as hydride donors

被引：18

作者：

Zhang, Ying ^{[1
]}

Jiang, Xiao ^{[1
]}

Wang, Jin-Mei ^{[1
]}

Chen, Jing-Lei ^{[1
]}

Zhu, Yong-Ming ^{[1
]}

机构：

[1] Soochow Univ, Coll Pharmaceut Sci, Suzhou 215123, Peoples R China

来源：

RSC ADVANCES | 2015年 / 5卷 / 22期

关键词：

CARBON-MONOXIDE; REDUCTIVE CARBONYLATION; ORGANIC HALIDES; VINYL HALIDES; FORMYLATION; HYDROXYCARBONYLATION; ALKOXYCARBONYLATION; CHLORIDES; PROTOCOL; ALKENYL;

D O I：

10.1039/c4ra16388e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient one-pot palladium-catalyzed hydroformylation of aryl halides to produce aromatic aldehydes has been achieved, employing tert-butyl isocyanide as a C-1 resource and formate salt as a hydride donor without any additional bases. Characterized by its mild reaction conditions, easy operation and lower toxicity, this reaction can tolerate a wide array of functional groups with moderate to excellent yields.

引用

页码：17060 / 17063

页数：4

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