Photocatalytic Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran over Nb2O5 under Visible Light

被引：117
|
作者：
Zhang, Huili [1 ]
Wu, Qi [1 ]
Guo, Cong [1 ]
Wu, Ying [1 ]
Wu, Tinghua [1 ]
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2017年 / 5卷 / 04期
关键词：
5-Hydroxymethylfurfural; 2,5-Diformylfuran; Photocatalytic oxidation; Visible light irradiation; Nb2O5; MODIFIED TIO2 PHOTOCATALYSTS; EFFICIENT AEROBIC OXIDATION; CONVERSION; COMPOSITE; BIOMASS; MECHANISM; CELLULOSE; ALCOHOLS; FUELS; OXIDE;
D O I：
10.1021/acssuschemeng.7b00231
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photocatalytic selective oxidation of biomass derivate compound 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran is an environmentally friendly and energy-saving process. Nb2O5 was prepared and applied in the oxidation of HMF under visible light, although its bandgap energy is higher than 3.2 eV. The reaction process follows a special mechanism over a Nb2O5 catalyst different from the normal oxide semiconductor. The effect of calcination temperature, incident wavelength, and reaction time on photocatalytic performance was investigated. Nb2O5-800 exhibits the best performance in the presence of O-2 with benzotrifluoride as a solvent under visible light irradiation.
引用
收藏
页码：3517 / 3523
页数：7
相关论文
共 50 条
  • [41] Oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran with molecular oxygen in the presence of N-hydroxyphthalimide
    Kornpanets, M. O.
    Kushch, O. V.
    Litvinov, Yu E.
    Pliekhov, O. L.
    Novikova, K. V.
    Novokhatko, A. O.
    Shendrik, A. N.
    Vasilyev, A. V.
    Opeida, I. O.
    CATALYSIS COMMUNICATIONS, 2014, 57 : 60 - 63
  • [42] Efficient oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran using Mn(III)-salen catalysts
    Amarasekara, Ananda S.
    Green, Dalkeith
    McMillan, Erinn
    CATALYSIS COMMUNICATIONS, 2008, 9 (02) : 286 - 288
  • [43] In Situ Topochemical Transformation of ZnIn2S4 for Efficient Photocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran
    Zhu, Yanwei
    Deng, Wenfang
    Tan, Yueming
    Shi, Jianqiao
    Wu, Jingcheng
    Lu, Wenbo
    Jia, Jianfeng
    Wang, Shuangyin
    Zou, Yuqin
    ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (45)
  • [44] Unconventional Rapid Synthesis of Layered Manganese Dioxide Nanostructures for Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran
    Rodriguez, Armando Campos
    Qiu, GuoBin
    Nirjhar, Ahsiur Rahman
    Islam, Md. Tohidul
    Laughlin, Josh
    Sahriar, Miah Abdullah
    Nishat, Sadiq Shahriyar
    Mullick, Kankana
    Poyraz, Altug S.
    Ahmed, Saquib
    Biswas, Sourav
    ACS APPLIED NANO MATERIALS, 2023, 6 (17) : 15906 - 15915
  • [45] An Anderson-type polyoxometalate triggers aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran
    Sun, Yanbin
    Zheng, Jianfeng
    Xu, Jiajia
    Yang, Kaixuan
    Zhu, Zhiguo
    Su, Ting
    Ge, Hui
    Ren, Wanzhong
    Lu, Hongying
    FUEL, 2022, 315
  • [46] Cu catalyzed oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran and 2,5-furandicarboxylic acid under benign reaction conditions
    Hansen, Thomas S.
    Sadaba, Irantzu
    Garcia-Suarez, Eduardo J.
    Riisager, Anders
    APPLIED CATALYSIS A-GENERAL, 2013, 456 : 44 - 50
  • [47] Photocatalytic selective oxidation of biomass-derived 5-hydroxymethylfurfural to 2,5-diformylfuran on metal-free g-C3N4 under visible light irradiation
    Wu, Qi
    He, Yiming
    Zhang, Huili
    Feng, Zhiyuan
    Wu, Ying
    Wu, Tinghua
    MOLECULAR CATALYSIS, 2017, 436 : 10 - 18
  • [48] Palygorskite-supported ruthenium catalysts for the efficient selective oxidation of 5-hydroxymethylfurfural to 2, 5-diformylfuran
    Zhong, Xuemin
    Yuan, Peng
    Sadjadi, Samahe
    Liu, Dong
    Wei, Yanfu
    APPLIED CLAY SCIENCE, 2023, 242
  • [49] The functional and synergetic optimization of the thermal-catalytic system for the selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran: a review
    Zhang, Weijie
    Qian, Hengli
    Hou, Qidong
    Ju, Meiting
    GREEN CHEMISTRY, 2023, 25 (03) : 893 - 914
  • [50] Aerobic Selective Oxidation of Biomass-derived 5-Hydroxymethylfurfural to 2,5-Diformylfuran with Active Manganese Dioxide Catalyst
    Zhang, Shengqing
    Li, Weifang
    Zeng, Xianhai
    Sun, Yong
    Lin, Lu
    BIORESOURCES, 2014, 9 (03): : 4656 - 4666
12345