Compressed Corannulene in a Molecular Cage

被引：62
|
作者：
Schmidt, Bernd M. [1 ]
Osuga, Takafumi [1 ]
Sawada, Tomohisa [1 ]
Hoshino, Manabu [1 ]
Fujita, Makoto [1 ]
机构：
[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 04期
关键词：
cage compounds; corannulenes; host-guest systems; supramolecular chemistry; pi interactions; SELF-ASSEMBLED CAGES; ORBITAL AXIS VECTOR; TO-BOWL INVERSION; GEODESIC POLYARENES; ELECTRON-TRANSPORT; COORDINATION CAGES; AROMATIC-MOLECULES; STACKS; DERIVATIVES; FULLERENES;
D O I：
10.1002/anie.201509963
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Self-assembled coordination cages can be employed as a molecular press, where the bowl-shaped guest corannulene (C20H10) is significantly flattened upon inclusion within the hydrophobic cavity. This is demonstrated by the pairwise inclusion of corannulene with naphthalene diimide as well as by the dimer inclusion of bromocorannulene inside the boxlike host. The compressed corannulene structures are unambiguously revealed by single-crystal X-ray analysis.
引用
收藏
页码：1561 / 1564
页数：4
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