Hydrogen assisted crack initiation in metals under monotonic loading: A new experimental approach

Hydrogen is foreseen as a promising energy carrier that can control global warming by reducing CO2 emissions. However, hydrogen is associated with an embrittlement phenomenon that imparts substantial damage to the infrastructure by reducing the ductility, fracture strength, strength bearing capacity, etc., of metallic components. Therefore, understanding hydrogen-induced crack initiation mechanisms in metals are of prime importance. Greater insights into this critical phenomenon are expected if the hydrogen-induced crack initiation can be correlated with the local microstructure and corresponding stress-strain state towards their propensity for hydrogen accumulation. With this motivation, in this work, crack initiation is studied for the uncharged and hydrogen charged nickel specimens during in-situ tensile loading under the scanning electron microscope. By assuming the material to be elastic at low strains, a novel approach is implemented for generating the micro structural stress maps through strain and stiffness tensor extracted at each point in the region of interest on the specimen surface using high-resolution digital image correlation (HR-DIC) and Euler angles (given by electron backscattered diffraction data), respectively. Based on this analysis at low strain, the crack initiation sites for uncharged and hydrogen charged nickel specimens are correlated with microstructural maps of maximum Schmid factor, elastic modulus in the loading direction, hydrostatic stress, von Mises stress, and triaxiality factor. The analysis highlighted two independent factors responsible for hydrogen enhanced decohesion (HEDE) based intergranular failure observed only at the random grain boundaries, (i) strain localization due to hydrogen enhanced localized plasticity (HELP) mechanism of hydrogen embrittlement, and (ii) hydrostatic stress-based hydrogen diffusion to the crack initiation sites. These critical insights thus can help to design hydrogen embrittlement resistant metals. In addition, the novel experimental approach can be used to calibrate advance micromechanical models while providing quantitative estimate of the hydrogen distribution in realistic metallic microstructure responsible for hydrogen-assisted crack initiation with deformation.