Synthesis and characterization of Co3(O2CCH2CH2PO3)2•6H2O, a metal carboxylate-phosphonate with a framework structure

被引:112
|
作者
Distler, A [1 ]
Sevov, SC [1 ]
机构
[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
关键词
D O I
10.1039/a801964i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound is the first carboxylate-phosphonate with an extended three-dimensional structure, a framework of trimers of edge-sharing CoO6-octahedra and organic species with two different functional groups, carboxylic and phosphonic, both coordinated to the metal atoms.
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页码:959 / 960
页数:2
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