Synthesis and characterization of Co3(O2CCH2CH2PO3)2•6H2O, a metal carboxylate-phosphonate with a framework structure

被引:112
|
作者
Distler, A [1 ]
Sevov, SC [1 ]
机构
[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
关键词
D O I
10.1039/a801964i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound is the first carboxylate-phosphonate with an extended three-dimensional structure, a framework of trimers of edge-sharing CoO6-octahedra and organic species with two different functional groups, carboxylic and phosphonic, both coordinated to the metal atoms.
引用
收藏
页码:959 / 960
页数:2
相关论文
共 50 条
  • [1] A study on the effects of drying conditions on the stability of NaNd(CO3)2•6H2O and NaEu(CO3)2•6H2O
    Fannin, C
    Edwards, R
    Pearce, J
    Kelly, E
    APPLIED GEOCHEMISTRY, 2002, 17 (10) : 1305 - 1312
  • [2] Synthesis and characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2
    Ayyappan, S
    de Delgado, GD
    Cheetham, AK
    Férey, G
    Rao, CNR
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (17): : 2905 - +
  • [3] Hydrothermal synthesis and crystal structure of two Co phosphonates containing trifunctional phosphonate anions:: Co3(O3PCH2NH2CH2PO3)2 and Co3(O3PCH2-NC4H7-CO2)2•5H2O
    Turner, A
    Jaffrès, PA
    MacLean, EJ
    Villemin, D
    McKee, V
    Hix, GB
    DALTON TRANSACTIONS, 2003, (07) : 1314 - 1319
  • [5] Co3(2-OOCC6H4PO3)2(H2O)3•H2O: A layered metal phosphonate showing reversible dehydration-rehydration behavior and ferrimagnetism
    Wang, Peng-Fei
    Cao, Deng-Ke
    Bao, Song-Song
    Jin, Hao-Jun
    Li, Yi-Zhi
    Wang, Tian-Wei
    Zheng, Li-Min
    DALTON TRANSACTIONS, 2011, 40 (06) : 1307 - 1312
  • [6] Synthesis and crystal structure of ((NH3CH2 CH2)3N)2P6O18•6H2O
    Marouani, H
    Rzaigui, M
    SOLID STATE SCIENCES, 1999, 1 (06) : 395 - 408
  • [7] Synthesis and crystal structure of the transition metal trimetaphosphimates Zn3[(PO2NH)3]2•14H2O and Co3[(PO2NH)3]2•14H2O
    Stock, N
    Irran, E
    Schnick, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (04): : 555 - 561
  • [8] Hydrothermal synthesis, crystal structure and fluorescent property of a new zinc carboxylate-phosphonate:: [Zn3(O3PCH(CH3)COO)2(H2O)]
    Lai Zhu-Zhi
    Fu Rui-Biao
    Sheng Tian-Lu
    Li Ya-Min
    Huang Xi-He
    Wu Xin-Tao
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (11) : 1397 - 1401
  • [9] Chains, planes, and tunnels of metal diphosphonates:: synthesis, structure, and characterization of Na3Co(O3PCH2PO3)(OH), Na3Mg(O3PCH2PO3)F•H2O, Na2Co(O3PCH2PO3)•H2O, NaCo2(O3PCH2CH2CH2PO3)(OH), and CO2(O3PCH2PO3)(H2O)
    Distler, A
    Lohse, DL
    Sevov, SC
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (11): : 1805 - 1812
  • [10] The synthesis and characterization of [4-CH3OC6H4CH2NH3]4P2O7•6H2O
    Selmi, A.
    Akriche, S.
    Rzaigui, M.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2006, 181 (09) : 2201 - 2211