Synthesis of palladium complexes with bis(diphenylphosphinomethyl) amino ligands: A catalyst for the Heck reaction of aryl halide with methyl acrylate

被引：30

作者：

Keles, Mustafa ^{[1
]}

Aydin, Ziya ^{[1
]}

Serindag, Osman ^{[1
]}

机构：

[1] Cukurova Univ, Fac Sci & Letters, Dept Chem, TR-01330 Adana, Turkey

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 10期

关键词：

bis(diphenylphosphinomethyl)amino; Pd complex; Heck reaction; aryl halide;

D O I：

10.1016/j.jorganchem.2007.01.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of ligands, (Ph2PCH2)(2)NR (R = -CH3) (1), -C(CH3)(3), (2) -m-C6H4SO3Na (3), and their Pd(II) complexes have been synthesized under nitrogen atmosphere using Schlenk method. All compounds were characterized using elemental analysis and spectroscopic techniques (AAS, NMR (H-1, P-31)). Based on the analysis the complexes have been proposed as in square planar geometry. The Pd(II) complexes were applied to the Heck reaction of aryl halide (Br, Cl) with methyl acrylate. The results have exhibited that complexes [PdCl2((Ph2PCH2)(2)NCH3)] (4) and [PdCl2((Ph2PCH2)(2)NC(CH3)(3))] (5) have shown higher turnover numbers (TON) than complex [PdCl2(Ph2PCH2)(2)N-m-C6H4SO3Na] (6). (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1951 / 1955

页数：5

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