Synthesis and Crystal Structure Characterization of 3,5-Bis(2-quinolyl)-1,2,4-triazole

被引：11
|
作者：
Cheng, Hui-Min [1 ]
Zhu, Dun-Ru [1 ,2 ]
Lu, Wei [1 ]
Xu, Ren-Hui [1 ]
Shen, Xuan [1 ]
机构：
[1] Nanjing Univ Technol, State Key Lab Mat Oriented Chem Engn, Coll Chem & Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
[2] Huaiyin Normal Univ, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Jiangsu, Peoples R China
来源：
JOURNAL OF HETEROCYCLIC CHEMISTRY | 2010年 / 47卷 / 01期
基金：
中国国家自然科学基金;
关键词：
DINUCLEAR NICKEL(II) COMPLEX; MAGNETIC-PROPERTY; CHEMISTRY;
D O I：
10.1002/jhet.262
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first quinolyl substituted 1,2,4-triazole, 3,5-bis(2-quinolyl)-1,2,4-triazole (4), was synthesized from 2-cyanoquinoline (1) through an intermediate 2-quinolylhydrazidine (2) with 60.4% yield in a simple way. In the synthetic process of 4, another new intermediate, 1,4-diamino-1,4-bis(2-quinolyl)-2,3-diaza-1,3-butadiene (3) was obtained in a yield of 81.5%. Additionally, the absolute configurations of both 3 and 4 were determined by X-ray crystallography.
引用
收藏
页码：210 / 213
页数：4
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