PVTx properties in the gas phase for difluoromethane (HFC-32) plus pentafluoroethane (HFC-125)

被引:8
|
作者
Meng, L [1 ]
Duan, YY [1 ]
Chen, Q [1 ]
机构
[1] Tsing Hua Univ, Dept Thermal Engn, Key Lab Thermal Sci & Power Engn, Beijing 100084, Peoples R China
来源
关键词
D O I
10.1021/je0497505
中图分类号
O414.1 [热力学];
学科分类号
摘要
Gaseous PVT property measurements for difluoromethane (HFC-32) + pentafluoroethane (HFC-125) mixtures at 0.8191 (66.25 mass %), 0.5794 (37.38 mass %), and 0.4320 (24.79 mass %) mole fractions of HFC-32 are presented. Two hundred PVTx data points of this binary system were measured using Burnett isochoric methods in the range of temperature from (303.15 to 373.15) K, for pressures up to 3.246 MPa, and for densities up to 121 kg(.)m(-3). The experimental uncertainties are estimated to be within +/-10 mK for temperature, +/-0.3 kPa for pressure, 10.10% for density, and 0.1 mol % for composition. The temperature dependence of the second and third virial coefficients, along with the cross second and third virial coefficients, was also determined.
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页码:1821 / 1826
页数:6
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