Rigid π-conjugated mono-, bis-, and tris(2,2′:6′,2"-terpyridines)

被引:70
|
作者
Winter, Andreas
Egbe, Daniel A. M.
Schubert, Ulrich S.
机构
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] LMU Munchen, Ctr Nanosci, D-80333 Munich, Germany
关键词
D O I
10.1021/ol0707261
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A set of rigid, pi-conjugated linear mono- and bisterpyridines and star-shaped tristerpyridines have been synthesized using Pd(0)-catalyzed coupling reactions and the Horner-Wadsworth-Emmons reaction. The terpyridyl ligands obtained feature strong emission in the blue range with high quantum yields in dilute solution and thin films.
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页码:2345 / 2348
页数:4
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