RhCl(CO)(PPh3)2 catalyzed α-alkylation of ketones with alcohols

被引：32
|
作者：
Wang, Rui [1 ]
Huang, Lina [1 ]
Du, Zhengyin [1 ]
Feng, Hua [1 ]
机构：
[1] Northwest Normal Univ, Key Lab Ecoenvironm Related Polymer Mat, Minist Educ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 846卷
基金：
中国国家自然科学基金;
关键词：
Alkylation; Ketones; Alcohols; Hydrogen transfer; Cross coupling; LIGAND; NANOPALLADIUM; ACTIVATION; PRODUCTS; COMPLEX; ROUTE; PHASE;
D O I：
10.1016/j.jorganchem.2017.05.055
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A simple and efficient method for alpha-alkylation of ketones with primary alcohols catalyzed by RhCl(CO)(PPh3)(2) without additional additives under mild conditions is developed. It has a wide substrate scope, high atom-efficiency and chemoselectivity. It is an environmentally friendly method to build C-C bond because water is the only byproduct. (C) 2017 Published by Elsevier B.V.
引用
收藏
页码：40 / 43
页数：4
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