Cobalt(II) single-molecule magnets

被引：533

作者：

Murrie, Mark ^{[1
]}

机构：

[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

来源：

CHEMICAL SOCIETY REVIEWS | 2010年 / 39卷 / 06期

基金：

英国科学技术设施理事会; 英国工程与自然科学研究理事会;

关键词：

HIGH-SPIN MOLECULES; ANISOTROPY BARRIER; SMM BEHAVIOR; COMPLEXES; MAGNETIZATION; CLUSTERS; CAGE; CO; CHEMISTRY; SYMMETRY;

D O I：

10.1039/b913279c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This short tutorial review covers recent progress in the field of polynuclear cobalt(II)-based complexes, which display slow magnetic relaxation at low temperature. Cobalt(II) single-molecule magnets (SMMs) can display much larger magnetic anisotropies and hence, potentially higher blocking temperatures than SMMs based on ions where the zero-field splitting originates from a second order spin-orbit coupling, such as manganese(III).

引用

页码：1986 / 1995

页数：10

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