Is the unexpected behaviour of the resolved K3[CrIII(C2O4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnIICrIII(C2O4)3 NEt(n-Pr)(n-Bu)(nC5H11)] network?

被引：5

作者：

Gruselle, M ^{[1
]}

Train, C

Ovanesyan, NS

Makhaev, VD

Cordier, C

机构：

[1] Univ Paris 06, CNRS, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France

[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

[3] Univ Paris 07, CNRS, UMR 7086, F-75005 Paris, France

来源：

MENDELEEV COMMUNICATIONS | 2004年 / 14卷 / 06期

关键词：

D O I：

10.1070/MC2004v014n06ABEH002035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Racemic and resolved [Ce-II(C2O4)(3)]K-3 dissolved in water were investigated by IR spectroscopy. Compared to the racemic compound, the spectrum of the resolved one exhibits additional peaks, which have a complex temporal evolution. These peaks are attributed to water molecules coordinated to the metal ion and tentatively related to the formation of a pure chiral solid phase of two-dimensional (213) oxalate-based Mn-Cr networks starting from partially resolved [CrIII(C2O4)(3)](3-).

引用

页码：284 / 285

页数：2

共 50 条

[41] Ln2(C2O4)2(pyzc)2(H2O)2]n [Ln = Pr (1), Er (2)]:: Novel two-dimensional lanthanide coordination polymers with 2-pyrazinecarboxylate and oxalate
Li, Bing
Gu, Wen
Zhang, Li-Zhi
Qu, Jie
Ma, Zhen-Ping
Liu, Xin
Liao, Dai-Zheng
INORGANIC CHEMISTRY, 2006, 45 (26) : 10425 - 10427
[42] Crystal structure of bis[tris(ethylenediamine)cobalt(III)] pentaoxalatocobaltate(II) tetrahydrate, [Co(C2H8N2)3]2[Co2(C2O4)5] • 4H2O
Kang, Jaeun
Pyo, Seungmoon
Yun, Hoseop
Do, Junghwan
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (03): : 353 - 354
[43] Preparation and X-ray crystal structure of the polymeric zirconium(IV) oxalate complex [K-2{Zr(C2O4)(3)}center dot H2C2O4 center dot H2O](n)
Baggio, R
Garland, MT
Perec, M
INORGANIC CHEMISTRY, 1997, 36 (04) : 737 - 739
[44] Neutron polarization analysis of the magnetic ordering of the quasi-two-dimensional honeycomb network d20-(P(C6D5)4) FeIIFeIII(C2O4)3
Department of Physics, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, United Kingdom
不详
不详
Phys B Condens Matter, (266-269):
[45] Neutron polarisation analysis of the magnetic ordering of the quasi-two-dimensional honeycomb network d20-(P(C6D5)4) FeIIFeIII(C2O4)3
Visser, D
Carling, SG
Watts, ID
Day, P
Andersen, KH
PHYSICA B-CONDENSED MATTER, 1999, 267 : 266 - 269
[46] Solid state formation of calcium ferrites from thermal decomposition of mixtures Ca3(C6H5O7)2•4H2O-Fe2(C2O4)3•6H2O -: The role of mechanical activation on the mechanism of the thermal decomposition and the temperature of the ferrites formation
Berbenni, V.
Marini, A.
Bruni, G.
Milanese, C.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2008, 82 (02) : 255 - 259
[47] A novel three-dimensional metal-organic framework constructed from two-dimensional interpenetrating layers based on trinuclear cobalt clusters:: [Co3(btec)(C2O4)(H2O)2]n
Li, YG
Hao, N
Wang, EB
Lu, Y
Hu, CW
Xu, L
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (14) : 2567 - 2571
[48] Muon spin rotation in the molecular-based layer ferrimagnets AFe(II)Fe(III)(C2O4)3 (A = N(n-C4H9)4, P(C6H5)4)
Nuttall, CJ
Carling, SG
Day, P
SOLID STATE COMMUNICATIONS, 1999, 110 (01) : 39 - 43
[49] The Jahn-Teller Effect on One-dimensional Copper-Oxalate Framework Cu(μ-C2O4)[(CH3)2NCH2CH2N(CH3)2]•4H2O
Zhang, Bin
Zhang, Yan
Wang, Zheming
Wang, Dongwei
Sun, Yang
Liang, Tongling
Zhao, Zhijuan
Zhang, Xiaoyu
Qu, Baolong
Feng, Rongjuan
Li, Qiaolian
Luo, Xiaofei
Liu, Mei
Zhang, Xueying
Zhu, Daoben
XXVTH INTERNATIONAL SYMPOSIUM ON THE JAHN-TELLER EFFECT AND RELATED PHENOMENA, XXV-JAHN-TELLER, 2024, 2769
[50] 配位聚合物{[K（H2O）]3[Fe（C2O4）3]}_n结晶过程的原位微量热、结构及吸附性质
王豆豆
辛月坤
林泽
安秦东
李扬
解凤霞
化工技术与开发, 2025, 54 (03) : 28 - 33+43

← 1 2 3 4 5 →