Regioselective Activation of a Sterically More Hindered C-C Bond of Biphenylenes Using an Alkene as Both a Directing Group and a Reaction Moiety

被引：12
|
作者：
Takano, Hideaki [1 ]
Ito, Takeharu [1 ]
Kanyiva, Kyalo Stephen [2 ]
Shibata, Takanori [1 ]
机构：
[1] Waseda Univ, Sch Adv Sci & Engn, Dept Chem & Biochem, Shinjuku Ku, 3-4-1 Okubo, Tokyo 1698555, Japan
[2] Waseda Univ, Sch Adv Sci & Engn, Global Ctr Sci & Engn, Shinjuku Ku, 3-4-1 Okubo, Tokyo 1698555, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 57期
基金：
日本学术振兴会;
关键词：
biphenylene; C-C bond activation; hydrocarbons; regioselective; rhodium; CARBON-CARBON BONDS; CYCLOADDITION; OLEFINS; FUNCTIONALIZATION; TRANSFORMATIONS; CARBOACYLATION; COMPLEXES; MECHANISM; INSERTION; PLATINUM;
D O I：
10.1002/chem.201804044
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Rh-catalyzed intramolecular reaction of 1-(2-vinylaryl)-substituted biphenylenes was used to construct a dihydrobenzo[b]fluoranthene skeleton. This transformation was achieved by regioselective C-C bond cleavage of a sterically more hindered biphenylene site by using alkene as both a directing group and a reaction moiety. Furthermore, we measured and analyzed the photophysical properties of the new multicyclic fused compounds.
引用
收藏
页码：15173 / 15177
页数：5
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