Ligand-Controlled, Tunable Silver-Catalyzed C-H Amination

被引：108

作者：

Alderson, Juliet M. ^{[1
]}

Phelps, Alicia M. ^{[1
]}

Scamp, Ryan J. ^{[1
]}

Dolan, Nicholas S. ^{[1
]}

Schomaker, Jennifer M. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 48期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; WHITE-LIGHT EMISSION; AGGREGATION-INDUCED EMISSION; ALTERNATIVE APPROACH; EMITTING-DIODES; PHOTOLUMINESCENCE; PHOSPHOR; EFFICIENT; FLUORESCENCE; GREEN;

D O I：

10.1021/ja5094309

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of readily tunable and regioselective C-H functionalization reactions that operate solely through catalyst control remains a challenge in modern organic synthesis. Herein, we report that simple silver catalysts supported by common nitrogenated ligands can be used to tune a nitrene transfer reaction between two different types of C-H bonds. The results reported herein represent the first example of ligand-controlled and site-selective silver-promoted C-H amination.

引用

页码：16720 / 16727

页数：8

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