Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K and its compounds

被引：0
|
作者：
Wang, H [1 ]
Duan, JX
Ran, XQ
Gao, SY
机构：
[1] NW Univ Xian, Dept Chem, Shaanxi Key Lab Physico Inorgan Chem, Xian 710069, Peoples R China
[2] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
[3] Chinese Acad Sci, Qinghai Inst Salt Lakes, Xian 710043, Shaanxi, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2004年 / 22卷 / 10期
关键词：
solubility diagram of quaternary system; double salts; cesium chloride and yttrium chloride; compound Cs4YCl7 center dot 10H(2)O and Cs3Y2Cl9 center dot 14H(2)O;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The equilibrium solubility of one CsCl-YCl3-H2O ternary section Of CsCl-YCl3-9.5%HCl-H2O quaternary system at T=298.15 K was investigated by the physico-chemical analysis method and the corresponding phase diagram was plotted. The crystallization of two new double salts Cs4YCl7.10H(2)O (4 : 1 type) and Cs3Y2Cl9.14H(2)O (3 : 2 type) was successful and they were obtained from the complicated system directly. Both were identified and characterized by X-ray, thermal analysis method of TG-DTG, DSC. The fluorescence experiments show that up-conversion phenomenon does not exist in compounds CS4YCl7.10H(2)O and Cs3Y2Cl9.14H(2)O.
引用
收藏
页码：1128 / 1132
页数：5
相关论文
共 50 条
  • [21] Study on the Phase Diagram of CsCl-CeCl3-HCl（11%）-H2O System and the Properties of the Compounds
    王惠
    段锦霞
    冉新权
    高世扬
    Chinese Journal of Chemistry, 2002, (09) : 904 - 908
  • [22] Thermodynamics and Phase Equilibrium of the System CsCI-MgCl2-H2O at 298.15 K
    Guo, Lijiang
    Wang, Yaxiao
    Tu, Lanying
    Li, Jianqiang
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2017, 62 (04): : 1397 - 1402
  • [23] Studies on quaternary system CsCl-PrCl3-13%HCl-H2O (25 degrees C) and CsCl-PrCl3-42%HAc-H2O (30 degrees C)
    Li, YH
    Ran, XQ
    Chen, PH
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1997, 18 (03): : 353 - 356
  • [24] Pitzer thermodynamic model of the system HCl-NaCl-CaCl2-H3BO3-H2O at 298.15 K and its application
    Li D.
    Sun S.
    Zhang T.
    Zhao Y.
    Meng L.
    Guo Y.
    Deng T.
    Meng, Lingzong (menglingzong@lyu.edu.cn), 1600, Materials China (72): : 3160 - 3169
  • [25] HETERONUCLEAR COMPLEXES IN (MOO3+)-(TI3+)-HCL-H2O SYSTEM
    CHICHIROVA, ND
    TIKHONOVA, VP
    SALNIKOV, YI
    TRACHEVSKII, VV
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1992, 35 (06): : 16 - 19
  • [26] AS(III)-HCL-H2O SYSTEM .3. THE LIQUID LIQUID-STATE
    RADU, O
    GHEORGHIU, C
    REVUE ROUMAINE DE CHIMIE, 1991, 36 (1-3) : 43 - 48
  • [27] A NONEQUILIBRIUM PHASE-DIAGRAM OF THE SYSTEM HCL-H2O DETERMINED BY H-1-NMR
    HANSEN, EW
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1988, 33 (02): : 99 - 104
  • [28] Phase Equilibrium in the System RbCl-NdCl3-HCl(13.26%)-H2O at 298.15 K and Standard Molar Enthalpy of Formation of New Solid Phase Compound
    Xie, Hai-Quan
    Yang, Qi-Chao
    Qiao, Zhan-Ping
    Chen, Xin
    Zhang, Ping-Yun
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (09): : 3235 - 3238
  • [29] Solubility and Phase Equilibrium Investigation of the Ternary System CsCl-MgCl2-H2O at T=273.15, 308.15, and 348.15 K
    Li, Hongxia
    Guo, Lijiang
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2020, 65 (06): : 2983 - 2989
  • [30] Phase Diagram of AlCl3-FeCl3-H2O(-HCl) Salt Water System at 298.15 K and Its Application in the Crystallization of AlCl3•6H2O
    Cheng, Huaigang
    Wu, Lixiang
    Cao, Liqiong
    Zhao, Jing
    Xue, Fangbin
    Cheng, Fangqin
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2019, 64 (12): : 5089 - 5094
12345