Esr measurements of C-60(-) anion crystals

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作者
Kodama, T
Kato, M
Kato, T
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O64 [物理化学(理论化学)、化学物理学];
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070304 ; 081704 ;
摘要
The anisotropic components of the g factor of C-60(-) were determined with accuracy from the analysis of angular dependent ESR spectra of single crystal C-60(-) salts. The evaluation of the g factor was performed according to the classification of symmetry of the C-60(-) geometry. It was found out from the evaluation that the molecular structure of C-60(-) should be distorted to the lower symmetry of C-2h or C-i. This conclusion was well explained theoretically by the ab initio MO calculations.
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页码:185 / 190
页数:6
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