New Method for Silicon Nitride Synthesis Via Hybrid Polymer Nanocomposites

被引:0
|
作者
Radu, Anita-Laura [1 ]
Sarbu, Andrei [1 ]
Motoc, Stefania [2 ]
Mara, Luminita [3 ]
Fruth-Oprisan, Victor [4 ]
Garea, Sorina Alexandra [5 ]
Dima, Stefan Ovidiu [1 ]
Nechifor, Gheorghe [5 ]
Sarbu, Liliana [1 ]
Iovu, Horia [5 ]
机构
[1] Natl Res & Dev Inst Chem & Petrochem ICECHIM, Polymers Dept, Bucharest, Romania
[2] Met Res Inst, Bucharest 060021, Romania
[3] Natl Res Dev Inst Nonferrous & Rare Met IMNR, Pantelimon, Romania
[4] Romanian Acad, Phys Chem Inst Ilie Murgulescu, Bucharest 060021, Romania
[5] Univ Politehn Bucuresti, Appl Chem & Mat Sci Fac, Bucharest 010072, Romania
关键词
radical polymerization; nanocomposite; silica; silicon nitride;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Mesoporous silica was obtained by the acid attack of a serpentinite rock. This material was soaked with acrylonitrile (containing azobisisobutyronitrile as initiator) and the radical polymerization led to the obtaining of polymer inorganic-organic nanocomposites. The polymer nanocomposites were transformed in carbon-silica nanocomposites by the cyclization and graphitization of the carbon chain polymer. Heating the carbon-silica nanocomposite in nitrogen atmosphere allowed the synthesis of silicon nitride, a raw material for special ceramics.
引用
收藏
页码:167 / 172
页数:6
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