A Facile Synthesis Procedure for Sulfonated Aniline Oligomers with Distinct Microstructures

被引：7

作者：

Karunagaran, Ramesh ^{[1
]}

Coghlan, Campbell ^{[2
]}

Tran, Diana ^{[1
]}

Tran Thanh Tung ^{[1
]}

Burgun, Alexandre ^{[2
]}

Doonan, Christian ^{[2
]}

Losic, Dusan ^{[1
]}

机构：

[1] Univ Adelaide, Sch Chem Engn, Adelaide, SA 5005, Australia

[2] Univ Adelaide, Sch Chem, Adelaide, SA 5005, Australia

来源：

MATERIALS | 2018年 / 11卷 / 09期

基金：

澳大利亚研究理事会;

关键词：

polyaniline; sulfonated polyaniline; microstructures; phenazine; pH; POLYANILINE NANOSTRUCTURES; NANOTUBES; GRAPHENE; WATER; ELECTROPOLYMERIZATION; POLYMERIZATION; NANOFIBERS; MORPHOLOGY; ELECTRODE; METHANOL;

D O I：

10.3390/ma11091755

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Well-defined sulfonated aniline oligomer (SAO) microstructures with rod and flake morphologies were successfully synthesized using an aniline and oxidant with a molar ratio of 10:1 in ethanol and acidic conditions (pH 4.8). The synthesized oligomers showed excellent dispersibility and assembled as well-defined structures in contrast to the shapeless aggregated material produced in a water medium. The synergistic effects among the monomer concentration, oxidant concentration, pH, and reaction medium are shown to be controlling parameters to generate SAO microstructures with distinct morphologies, whether micro sheets or micro rods.

引用

页数：11

共 50 条

[41] Low temperature facile synthesis of ZnO nuts and needle like microstructures
Karthik, T. V. K.
Rodriguez Lugo, Ventura
Hernandez, A. G.
Navarro Jimenez, J. L.
Sanchez-Campos, D.
Gomez Pozos, Heberto
Mendoza Anaya, D.
Cerecedo-Saenz, E.
MATERIALS LETTERS, 2019, 246 : 56 - 59
[42] Facile synthesis of gold nanoplates by thermally reducing AuCl4- with aniline
Xu, Kang
Guo, Zhi rui
Gu, Ning
CHINESE CHEMICAL LETTERS, 2009, 20 (02) : 241 - 244
[43] Facile synthesis of leaf-like cobalt microstructures at low temperature
Cheng, Guobin
MICRO & NANO LETTERS, 2014, 9 (05) : 312 - 314
[44] Synthesis and properties of bis(aniline, methyl)siloxy-octaphenylsilsesquioxane containing thermosetting polyimide oligomers
Yandek, Gregory R.
Haddad, Timothy S.
Guenthner, Andrew J.
Mabry, Joseph M.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
[45] Facile and efficient synthesis of star-shaped oligomers from a triazine core
Rim, Chinwon
Son, David Y.
TETRAHEDRON LETTERS, 2009, 50 (28) : 4161 - 4163
[46] One-step synthesis of hollow nanostructured aniline oligomers and their derived nitrogen doped carbon
Xing, Shuangxi
Chen, Lin
Huang, Lei
Wang, Tian
Yu, Xiaodan
Zhang, Yuxin
Xing, Yan
SYNTHETIC METALS, 2017, 227 : 170 - 176
[47] Divergent Synthesis of Functionalized Quinolines from Aniline and Two Distinct Amino Acids
Xiang, Jia-Chen
Wang, Zi-Xuan
Cheng, Yan
Xia, Shi-Qing
Wang, Miao
Tang, Bo-Cheng
Wu, Yan-Dong
Wu, An-Xin
JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (17): : 9210 - 9216
[48] Facile Synthesis of Hyperbranched Ethylene Oligomers and Ethylene/Methyl Acrylate Co-oligomers with Different Microscopic Chain Architectures
Fan, Huijun
Chang, Guanru
Bi, Huiqin
Gui, Xu
Wang, Hui
Xu, Guoyong
Dai, Shengyu
ACS POLYMERS AU, 2022, 2 (02): : 88 - 96
[49] Synthesis of sulfonated porous carbon nanospheres solid acid by a facile chemical activation route
Chang, Binbin
Guo, Yanzhen
Yin, Hang
Zhang, Shouren
Yang, Baocheng
JOURNAL OF SOLID STATE CHEMISTRY, 2015, 221 : 384 - 390
[50] Facile and scalable synthesis of baphicacanthin A by a two-pot procedure
Cuan, Yalong
Li, Wenhao
Dou, Yingchao
Yang, Guanyu
NATURAL PRODUCT RESEARCH, 2023, 37 (09) : 1439 - 1443

← 1 2 3 4 5 →